氮化硅添加对定向梯度多孔碳化硅陶瓷制备的影响.docVIP

  氮化硅添加对定向梯度多孔碳化硅陶瓷制 备的影响#  刘波波，杨建锋  ** 5 10 15 20 25 30 （金属材料强度国家重点实验室，西安交通大学，西安，710049） 摘要：利用高温重结晶工艺以氮化硅做造孔剂成功制得定向梯度多孔碳化硅陶瓷，研究 Si3N4添加量对定向 多孔碳化硅陶瓷组织结构和性能的影响。结果表明通过添加 Si3N4获得的多孔碳化硅陶瓷具有气孔率高、从 底部到顶部的孔径尺寸和孔密度连续梯度分布、气孔定向排列的特点。随着 Si3N4含量增加，烧失率逐渐增 大、多孔碳化硅陶瓷中颗粒趋于圆润、孔隙也逐渐减小、颗粒之间的连接更加紧密。X 衍射分析表明，形 成的碳化硅晶体为α-SiC（6H）晶体。随氮化硅含量从 0%增加到 15%，多孔碳化硅陶瓷的总气孔率从 38.7% 增加到 45.1.%，而强度则从 38.2MPa 降低到 33.1MPa。 关键词：碳化硅；多孔陶瓷；高温再结晶 中图分类号：V254.2 Effect of Nitride addition on directional gradient porous silicon carbide ceramics LIU Bobo, YANG Jianfeng (State Key Laboratory for Mechanical Behavior of Materials, Xi’an Jiaotong University,Xi’an, 710049) Abstract: The directional SiC porous ceramics by the high-temperature recrystallization process using silicon nitride as pore formation agent. And the effect of Si3N4 on directional microstructure and performance of porous silicon carbide ceramic was examined by XRD, SEM analysis. The results showed that the obtained silicon carbide ceramic had high porosity, continuous gradient distribution of pore size and pore density from the bottom to the top, indicated the characteristics of aligned holes by the adding Si3N4. With the Si3N4 content increased, the rate of weight loss increased, and the silicon carbide particles tend to become rounded, pore size also decreases, the connection between the particles became more strong. X-ray diffraction analysis showed the diffraction peak of the silicon nitride crystal of α-SiC (6H). With the Si3N4 content increases from 0% to 15%, total porosity increase from 38.7% to 45.1% with the increased silicon nitride content, and strength decreased from 38.2MPa to 33.1MPa. Key words: SiC; Porous ceramics; High temperature recrystallization 0 引言 梯度材料是一种在结构、成分或者结构和成分两者都同时发生梯度过渡变化的工程材 35 料 [1-3] ，梯度多孔碳化硅陶瓷是典型的梯度材料，具有优异的性能，如高硬度、好的高温强 度、优异的高温抗氧化性、稳定的化学性能及低的热膨胀系数等，被广泛应用于装甲材料、 生物医学材料、梯度过滤材料及表面功能覆盖材料等方面[4-8]。梯度多孔陶瓷相比普通均匀 多孔陶瓷具有高的过滤效率和较小的气、液体通过时的压降及较高的陶瓷强度，尤其是具有 定向孔结构的梯度多孔陶瓷，过滤效率更高，还具有良好机械强度，因此定向孔结构的梯度 40 多孔陶瓷备受人们的关注和