超声空化及其催化臭氧氧化技术.pdfVIP

中国科技论文在线 超声空化及其催化臭氧氧化技术# 赵雷，李健强* （哈尔滨工业大学土木工程学院，哈尔滨 150080 ） 5 摘要：超声空化降解水中的化学污染物，尤其是难降解的有机污染物，是近年来发展起来的 一项新型水处理技术。作为一种有前景的水处理高级氧化技术，超声空化催化臭氧氧化在世 界各国已经引起了高度重视。本文概述了超声对物质的作用机制，详细介绍了超声空化现象 及其基本理论，包括空化类型、空化反应的位置和影响超声空化的因素，综述了超声空化催 10 化臭氧氧化技术的研究发展，包括不同目标反应物、影响因素、降解机理、反应动力学等， 提出了该联用技术的发展趋势。 关键词：水处理；超声空化；催化臭氧氧化；降解 中图分类号：X703 15 Ultrasonic cavitation and its catalytic ozonation processes ZHAO Lei, LI Jianqiang (School of Civil Engineering, Harbin Institute of Technology, Harbin 150080) Abstract: Ultrasonic cavitation for the degradation of chemical contaminants, specifically for organic contaminants, has been a novel water treatment process recently. As a promising advanced 20 oxidation technology for water treatment, catalytic ozonation by ultrasonic cavitation has been highly interested by some research groups around the world. In this paper, reaction mechanisms of ultrasound on matter are briefly discussed, and the phenomena and the basic theories of ultrasonic cavitation are introduced in detail including cavitation types, the position of cavitation reaction and influencing factors on ultrasonic cavitation. The paper also summaries the development of 25 research on catalytic ozonation by ultrasonic cavitation, including the different target organic compounds, influencing factors, degradation mechanism, reaction kinetics, and so on. It presents the developmental direction of this combination process in the future. Key words: water treatment; ultrasonic cavitation; catalytic ozonation; degradation 30 0 引言 声波，也就是通常所说的声音，是一种机械