光交联壳聚糖聚乙烯醇共混膜的制备与性能.pdfVIP

第 21 卷第 4 期 无 锡 轻 工 大 学 学 报 Vol. 21 　No. 4 　 　 　 　　　　 　 2002 年 7 月 Journal of Wuxi University of Light Industry 　 　 　　　　 Jul. 　2002 ( ) 文章编号 :1009 - 038X 2002 04 - 0384 - 05 　 光交联壳聚糖/ 聚乙烯醇共混膜的制备与性能 刘文辉 , 　刘晓亚 , 　杨 成 , 　陈明清 (江南大学 化学与材料工程学院 , 江苏 无锡 214036) 摘　要 : 将壳聚糖与感光性物质混合制成感光性壳聚糖 ,再与聚乙烯醇按一定比例共混、成膜并进行 ( ) ( ) 光交联 ,制备了系列壳聚糖 CTS / 聚乙烯醇 PVA 光交联共混膜 ,并对共混膜的结构和性能进行比 较. 结果表明 :重氮树脂系列 CTS/ PVA 光交联共混膜性能优于 CTS/ PVA 共混膜 ,且重氮树脂系列 CTS/ PVA 光交联共混膜有其独特的表面形貌. 孔结构的大小及形态与共混膜中CTS/ PVA 的比例、重 氮树脂的含量有关. 关键词 : 光交联 ; 壳聚糖; 聚乙烯醇; 共混膜 中图分类号:O 636 文献标识码 : A Preparation and Properties of Photocrosslinked Chitosan/ PVA Blend Films L IU Wenhui , 　L IU Xiaoya , 　YAN G Cheng , 　CHEN Mingqing ( School of Chemical and Material Engineering , Southern Yangtze University , Wuxi 214036 , China) Abstract : This article mainly deals with a kind of novel photosensitive chitosan made from the mixture of pho tosensitive compounds and chitosan. Several series of photocrosslinked chitosan/ poly vinyl alcohol (CTS/ PVA ) blend films were prepared and their structures were characterized. Mechanical experimental data indicated that the photocrosslinked films with diaozresin had exhibited better mechanical properties than the CTS/ PVA blended films. Moreover , a kind of interesting surficial structure on the photocrosslinked CTS/ PVA blend films with diazoresin was discovered. The pore size and morphology varied with the blend ratio and the content of diazoresin. ( ) Key w