【高分子材料与工程】【毕业设计+开题报告+文献综述】聚芳醚酮稀土配合物的制备及其荧光性能研究.doc

（20届） 毕业设计 聚芳醚酮稀土配合物的制备及其荧光性能研究 摘要：以含羧基的聚芳醚酮（PEK）为高分子配体以1,10-邻菲罗啉（Phen）为协同配体，以Eu3+为中心配位离子，并引入La3+协同配位离子，制备一种新的聚芳醚酮铕镧配合物（PEK-Eu3+0.5La3+4-Phen）。采用红外光谱、X-射线衍射、对制备的聚芳醚酮稀土配合物的结构进行表征，结果表明PEK 与Phen均与稀土离子发生了配位反应。通过荧光激发和发射谱图对PEK-Eu3+0.5La3+4-Phen的荧光性能进行了分析，结果表明PEK-Eu3+0.5La3+4-Phen能够发射出Eu3+的特征荧光，最大发射波长618 nm。进一步研究了PEK-Eu3+0.5La3+4-Phen体系中La3+对Eu3+的荧光发射的影响，结果表明La3+的引入可显著增强Eu3+的荧光，其荧光强度相应的聚芳醚酮铕配合物（PEK-Eu3+-Phen） polyaryletherketone Abstract：Using carboxyl-containing polyaryletherketone (PEK) as macromolecular ligand, 1,10-phenanthroline (Phen) as synergistic ligand, europium (Eu3+) as central ion and lanthanum (La3+) as synergistic ion, a novel europium-lanthanum-coordinated polyaryletherketone (PEK-Eu3+0.5La3+4-Phen) was prepared. Its structure was characterized by FTIR, XRD and TGA, which confirmed that both PEK and Phen were coordinated with rare earth ions. The fluorescence properties of PEK-Eu3+0.5La3+4-Phen were investigated by means of fluorescence excitation and emission spectroscopies. The results suggested that PEK-Eu3+0.5La3+4-Phen could exhibit the characteristic emission of Eu3+ ion under UV excitation and the maximum emission peak appeared at 618 nm. Moreover, the influence of La3+ ion on the fluorescence emission of Eu3+ ion in the PEK-Eu3+0.5La3+4-Phen system was studied. The results indicated that the emission intensity of Eu3+ ion was obviously enhanced by the introduction of La3+ ion, and the emission intensity at 618 nm of PEK-Eu3+0.5La3+4-Phen was about 7 times as high as that of PEK-Eu3+-Phen. Keywords: Polyaryletherketone; 1,10-phenanthroline; Rare earth complex; Fluorescence properties  目 录 1 论 1 1.1 概述 1 1.2 稀土聚合物材料研究现状 1 1.3 稀土聚合物材料的应用 4 1.4 课题研究内容及设想 5 2 实验部分 6 2.1 实验原料与试剂 6 2.2 测试仪器及方法 6 2.2.1 红外光谱测试 6 2.2.2 X射线衍射测试 6 2.2.3 热失重分析 6 2.2.4 荧光性能测试 6 2.3 聚芳醚酮铕镧配合物（PEK-Eu3+0.5La3+4-Phen）的合成 6 2.4 聚芳醚酮铕配合物（PEK-Eu3+-Phen）的合成 6 2.5 小分子铕镧配合物（Eu3+0.5La3+4-Phen）的合成 7 3 结果与讨论 8 3.1 聚芳醚酮铕镧配合物的红外光谱分析 8 3.2 聚芳醚酮铕镧配合物的X-射线衍射分析 9 3.3 聚芳醚酮铕镧配