【高分子材料与工程】【毕业设计+开题报告+文献综述】聚乙二醇聚氨酯的相变性能研究.docVIP

（20 届） 本科毕业设计 聚乙二醇/聚氨酯的相变性能研究 摘要：以单组分聚氨酯(PU)、聚乙二醇（PEG1000、PEG2000）为原料，采用溶液挥发法制备了相变功能膜。采用光学显微镜、差示扫描量热法（DSC）对聚乙二醇/聚氨酯复合膜的形态结构及相变行为进行了测试分析，结果表明：采用水为聚乙二醇的溶剂、丁酮为聚氨酯的溶剂，所制备的膜会出现相分离。采用丁酮为聚乙二醇及聚氨酯的共溶剂，所制备的膜结构均匀，不会出现相分离，成膜效果好，且所制备的膜具有良好的相变调温功能，其相变温度在23.3℃到41.5℃之间，相变温度的峰位置在36.5℃时左右。最后，将所制备的聚乙二醇/聚氨酯复合材料用于锦纶面料的涂层加工，测试表明，经聚乙二醇/聚氨酯复合材料涂层后的锦纶面料，具有较好的相变调温功能，调温范围在31℃左右。 关键词：聚氨酯、聚乙二醇、固-固相变材料、储热  Phase Change Properties of PEG/PU Composites Abstract：The phase change films were prepared by solvent evaporation method using the single-component polyurethane(PU)/polyethylene glycol (PEG1000、PEG2000) as a raw material.The phase change behaviors and morphology of the polyethylene glycol/polyurethane composite ?lms were investigated with differential scanning calorimetry (DSC) and optical microscopy. The results showed that the films prepared with water as the solvent of polyethylene glycol and butanone as the solvent of polyurethane will appear phase separation, while the films prepared with butanone as the co-solvent of both polyethylene glycol and polyurethane will not appear phase separation. The resulted films were uniform. All samples present the excellent phase transition and temperature condition function. The phase change temperature is from 23.3 ℃ to 41.5 ℃, the phase transition’s peak position is at 36.5 ℃. At last, the nylon fabric was coated by the PU/PEG composites. The results showed that nylon fabric coated by PU/PEG composite materials had excellent temperature condition function and the temperature control area is at about 31℃.朗显示对应的拉丁字符的拼音 Keywords: Polyurethane，polyethylene glycol，solid-solid phase change materials， heat storage  目录 目录 V 1. 序 言 1 2. 实验部分 5 2.1实验材料 5 2.2聚乙二醇/聚氨酯相变复合膜的制备 5 2.2.1 制作PEG溶液 5 2.2.2 面胶膜的制备： 5 2.2.3 底胶膜的制备： 5 2.3 调温功能锦纶涂层面料的制备 6 2.4 测试与分析 7 2.4.1显微镜观察 7 2.4.2、DSC测试 7 2.4.3调温功能测试 8 3.结果分析 10 3.1显微镜照片分析 10 3.2 DSC测试数据与测试图 12 3.3调温测试结果 14 4 结论 16 参考文献 17 致谢 18 1. 序 言 随着全球能源紧缺，节能技术已经成为全球关注的焦点。各种加热空气调节设备在使用中往往是消耗了大量的燃料和电力，为了减少这种不必要的浪费，提高人们的生活