【高分子材料与工程】【毕业设计+开题报告+文献综述】石蜡微胶囊的制备及性能表征.doc

（20届） 毕业设计 摘要： 14～30 的直链烷烃构成，由于其具有相变潜热大、价格便宜、无腐蚀、无污染等特点而成为理想的相变材料。同时作为被包裹的囊芯，可以克服石蜡本身导热系数低，可能被空气氧化为有机酸等缺点，所以石蜡类相变材料成为了一种较理想的微胶囊囊芯材料。石蜡相变微胶囊在太阳能存储、节能建筑材料、智能调温纤维、热功能流体和航空航天等领域有着广泛的应用。 本课题是在阅读了大量的文献之后，经过细致的甄选，采用界面聚合的方法，以石蜡为芯材，甲基丙烯酸甲酯-甲基丙烯酸共聚物（P( MMA-co-MAA)）为壳材，制备相变微胶囊。通过电子显微镜（SEM）、DSC、TGA、IR和粒径分析等方法测定相变微胶囊的物理性能和热性能。实验探讨了交联剂用量、原料浓度、芯壁比等制备过程参数对微胶囊各种性能的影响。 界面聚合法制备了以不同芯壁比预聚物为微胶囊壁材的相变微胶囊材料并进行了相关表征。实验结果表明：采用界面聚合法，以Span-60和Tween-60为乳化剂，芯壁比为4:3时，制备的MEPCM表面较光滑，粒径分布集中，相变潜热为132 J/g。新型MEPCM材料绿色环保、价廉易得，制备方法及工艺可行，产品应用面广，有较好的工业化前景。 关键词：  Preparation and characterization of paraffin phase change microcapsules Abstract：’s attention, as the exacerbating of energy crisis. Microencapsulated phase change material(MEPCM) is a shape-stabilized phase change material which is obtained by packaging technology of microcapsules. Paraffin is mainly made up of the linear paraffin which have 14 ~ 30 carbon number. Due to paraffin has a large latent heats, no corrosion, no pollution and cheap wait, it be the ideal phase change materials. At the same time, as the core material which was wrapped, paraffin can overcome the disadvantages of low thermal conductivity and easy to be oxidized to organic acid by air, so paraffin class phase change materials become a kind of ideal microcapsule core material. Paraffin phase change microcapsules material has been widely used in the fields of solar storage, energy saving building materials, smart thermostat fiber, heat-flow and aerospace. This project was chosen on the basis of a good acknowledgement of this field and the interface polymerization was used. Paraffin was selected as core and P( MMA-co-MAA) as shell. The physical properties and thermal properties of microencapsulates were investigated by Scanning Electronic Microscopy(SEM), Differential Scanning Calorimetry(DSC), Thermogravimetry Analysis(TGA), Fourier Transform Infrared Spectroscopy(FTIR)and so on. Experiments are done to study the effect of these factors, such as cross-linking agent, concentrat