以PHAs为固体碳源的城镇二级出水深度脱氮研究.pdfVIP

中国环境科学 2014,34(2) ：331~336 China Environmental Science 以 PHAs 为固体碳源的城镇二级出水深度脱氮研究 李 彭 1,唐 蕾 2,左剑恶 1*,袁 琳 3,李再兴 2 (1.清华大学环境学院,环境模拟与污染控制国家重点联合实验 室,北京 100084 ；2.河北科技大学环境科学与工程学院,河北省 石家庄 050018 ；3.浦华环保有限公司,北京 100020) 摘要：利用从连续运行的缓释碳源滤料滤池中取出的聚羟基脂肪酸酯(PHAs)颗粒,研究了微生物和硝酸盐对其的总有机碳(TOC)释放速率 的影响,并研究了温度、pH 值、硝态氮浓度对其反硝化速率的影响.结果表明:原有的和附着有微生物的 PHAs 颗粒在去离子水中 TOC 释 放速率分别为 0.030,0.053mg/(g·d),远低于水中有硝酸盐时的 TOC 释放速率[进水 NO3--N 为 30mg/L 时,TOC 释放速率为 0.533mg/(g·d)].温 度和 pH 值对反硝化速率影响较大, pH 值为 7.5 时,在 15~35℃范围内, 30℃下的反硝化速率最大,为 0.067mg/(g·h);温度为 30℃时,pH 值在 6.0~9.0 范围内,pH 值为 7.8 时的反硝化速率最大,达到 0.061mg/(g·h).反硝化速率与 NO3--N 浓度之间的关系符合 Monod 方程,最大反应速 率和半饱和常数分别为 4.74mgNO3--N/(gSS·h)和 56.6mg/L. 关键词：缓释碳源；固相反硝化；可生物降解聚合物；聚羟基脂肪酸酯；城镇二级出水 中图分类号：X703.5 文献标识码：A 文章编号：1000-6923(2014)02-0331-06 1 Tertiary nitrogen removal of the municipal secondary effluent using PHAs as solid carbon sources. LI Peng , TANG 2 1* 3 2 Lei , ZUO Jian-e , YUAN Lin , LI Zai-xing (1.State Key Joint Laboratory of Environmental Simulation and Pollution Control, School of Environment, Tsinghua University, Beijing 100084, China ；2.School of Environmental Science and Engineering, Hebei University of Science and Technology, Shijiazhuang 050018, China ；3.THUNIP Holdings Limited Company, Beijing 100020, China). China Environmental Science, 2014,34(2)：331~336 Abstract ：Polyhydroxyalkanoates (PHAs) pellets, which were taken from a denitrification biofilter with sustained-release carbon source materials, were used to investigate the effects of microbes and nitrate on the organic carbon release rate of PHAs and the effects of temperature, pH and NO3--N concentration on the denitrification rates. The results indicated that the total organi