用于地下水除氟的羟基磷灰石制备及其除氟效能.pdfVIP

中国环境科学 2014,34(1) ：58~64 China Environmental Science 用于地下水除氟的羟基磷灰石制备及其除氟效能 刘 成 1,2*,胡 伟 2,李俊林 2,姜成浩 2,陈 卫 1,2 (1.河海大学浅水湖泊综合治理与资源开发教育部重点实验 ,江苏 南京 210098 ；2.河海大学环境学院,江苏 南京 210098) 摘要：针对地下水中氟离子的去除分别合成了粉状和球状两种羟基磷灰石,利用红外光谱扫描、电镜扫描、X 射线衍射仪、X 射线能谱小 试实验分析其基本特征,并进一步利用小试实验确定其对水中氟离子的去除效能.结果表明,制备的粉状羟基磷灰石具有较高的纯度,但结 晶度相对较低;而球状羟基磷灰石则较为规则、带孔隙的球形颗粒,粒径约为 1mm 左右.粉状羟基磷灰石对徐州地下水中氟离子的去除容量 约为 15.2mg/g,且其去除速度较快,主要集中在 30min 以内;球状羟基磷灰石对地下水中氟离子的去除容量约为 7.5mg/g,但其去除过程持续 时间较长.利用粉状和球状羟基磷灰石组合的工艺可将地下水中的氟离子浓度降低至 0.8~0.9mg/L,且去除效果稳定.综上所述,粉状和球状 羟基磷灰石的组合工艺可用于地下中氟离子的去除. 关键词：地下水；氟；羟基磷灰石；除氟容量 中图分类号：X703.5 文献标识码：A 文章编号：1000-6923(2014)01-0058-07 Preparation of the hydroxyapatite to remove fluorine from groundwater and its removal performance. LIU Cheng1,2* 2 2 2 1,2 , HU Wei , LI Jun-lin , JIANG Cheng-hao , CHEN Wei (1.Key Laboratory of Integrated Regulation and Resource Development Shallow Lakes, Ministry of Education, Hohai University, Nanjing 210098, China ；2.College of Environment, Hohai University, Nanjing 210098, China). China Environmental Science, 2014,34(1)：58~64 Abstract ：Powdered and spherical hydroxyapatite were prepared in the lab for the removal of fluorine from groundwater, in addition, character and removal effect were determined using infrared spectrometer, scanning electron microscopy instrument, X ray diffraction, X-ray photoelectron spectrometer and batch scale experiment. The results show that, powdered hydroxyapatite prepared in lab had high purity but relatively low crystallinity, while the prepared spherical hydroxyapatite is relatively regular, porous spherical particles with particle size about 1mm. Removal capacity of