周期换向电絮凝法用于处理含铬废水研究.pdfVIP

中国环境科学 2014,34(1) ：118~122 China Environmental Science 周期换向电絮凝法用于处理含铬废水研究 * 虞少嵚,熊道文, 陈湘斌,游建军 ,熊 珊,王合德 ( 中国水电顾问集团中南勘测设计研究院,长沙 湖南 410014) 摘要： 以铁作为极板,采用周期换向电絮凝法处理含铬废水,考察了初始 pH 值, 电流密 ,处理时间,初始质量浓度及周期换向时间等因素的 2,处理时间为 3.0min,初始浓度为 40mg/l 时,总铬和六价铬的去除效果理想,去 影响.结果表明,在初始 pH 值为 8.0~9.0, 电流密度为 16.37A/m 除率均在 99.5% 以上;10~15min 的换向周期在一定程度上解决了极板钝化问题,可降低 10%~20%的能耗.实验结果表明周期换向电絮凝法 处理含铬废水效果好,且可降低能耗. 关键词： 电絮凝；废水；六价铬；总铬 中图分类号：X703.1 文献标识码：A 文章编号：1000-6923(2014)01-0118-05 Treatment of wastewater containing chromium with periodic reversal electrocoagulation. YU Shao-qin, XIONG * Dao-wen, CHEN Xiang-bin, YOU Jiang-jun , XIONG Shan, WANG He-de (Hydrochina Zhongnan Engineering Corporation, Changsha 410014, China). China Environmental Science, 2014,34(1)：118~122 Abstract ：Wastewater containing chromium was treated with periodic reversal electrocoagulation by using iron plate as electrode. Several affecting factors for the removal of chromium, such as initial concentration, pH, retention time, reversal period and current density were investigated. The results showed that the removal rates of total Chromium and Chromium (VI) were above 99.5% under initial concentration of 40 mg/L, pH of 8.0~9.0, retention time of 2min and current density of 16.37A/m2 . Furthermore, the electrode passivation was reduced with the reversal period of 10~15min, and the energy consumption decreased by 10%~20%. The experiment results indicated that periodic reversal electrocoagulation was effectively and energy-saving for treatment of wastewater containing chromium. Key words ：electrocoagulation ；wastewater ；hexavalent-chromium ；total chromium 电镀电解,有色冶炼,皮革制品等行业生产过 原水 pH 值,