杂化型聚氨酯改性材料制备及性能研究.pdf

摘 要 摘 要 本论文主要采用带有八个乙烯基的POSS 和烯键封段的聚氨酯自由基共聚， 合成了一系列POSS 基高分子材料。主要工作内容如下： 1. 对于PU 和POSS 基高分子研究进展进行了综述，并分析了POSS 增强的机理。 29 2. 分别采用FTIR 、 Si-NMR 和XRD 等方法对POSS 基高分子复合材料进行了 表征，显示复合材料为交联结构。利用DMTA 、TGA 和拉伸等测试手段研究 POSS 含量对材料热性能、模量、拉伸性能影响，发现其中POSS 加入配比为 4 wt %样品,有最高的Tg、耗能模量和最小的自由体积。 3. 采用混合偶联剂对聚氨酯改性，并对改性复合材料性能进行了表征。 关键词：倍半硅氧烷，聚氨酯，复合材料，杂化材料 I 杂化型聚氨酯改性材料制备及性能研究 Abstract A series of polyhedral oligomeric silsesquioxane-based PU hybrid composites and mixed coupling reagent modified PU composites were prepared. Their structure and properties were characterized and evaluated. The main contents of this dissertation include the following points: 1. The development of PU and POSS-based hyrid materials were reviewed in detail. POSS enhancement mechanism in hybrid materials was discussed. 2. A series of polyhedral oligomeric silsesquioxane-based PU hybrid composites were 29 prepared and their structures were characterized by FTIR 、Si-NMR and XRD. The composite film properties were evaluated by DMTA. The results show that 4 wt % POSS–containing composite display the highest glass transitions and energy consuming modulus. 3. Mixed coupling reagent modified PU composites were prepared and their structure and properties were characterized and evaluated. Key words: POSS, PU, composite, hybrid II 目录 目录 摘 要 Ι Abstract ΙΙ 第一章 绪 论1 1.1 引言1 1.2 聚氨酯的改性研究现状：1 1.2.1 有机硅氧烷-PU 改性2 1.2.2 环氧树脂-PU 改性5 1.2.3 含氟化合物8 1.3 POSS 单体