表面机械研磨处理制备纳米晶Ni表层磁性能的研究.pdfVIP

O42 表面机械研磨处理制备纳米晶 Ni 表层磁性能的研究 李 伟 1 刘 平 1 戎咏华 2 马凤仓 1 刘新宽 1 （1.上海理工大学 材料科学与工程学院，上海，200093；2.上海交通大学 材料科学与工程学院， 上海，200240） 摘要：通过表面机械研磨处理(SMAT)工艺在 Ni 样品上制备出一层纳米晶表层，组织和成分分析显示不锈钢球上 的Fe 等元素在表面机械研磨处理过程中能扩散和渗入 Ni 样品表层，Fe 等元素高温下能在 Ni 表层内进一步扩散 和均匀化，并能与 Ni 元素结合成新型合金。新合金的形成导致 Ni 样品表层磁性能的变化，研究表明：经机械研 磨处理的纳米晶 Ni 表层的居里温度可达 600℃以上，远高于粗晶纯Ni 的 354.3℃，显示了表面机械研磨处理不仅 是一种表面纳米化工艺，而且是一种有效的表面改性工艺。 关键词：表面机械研磨处理; 纳米晶材料; 扩散; 磁性能 Research on magnetic property of nanocrystalline Nickel produced by surface mechanical attrition treatment 1 1 2 1 1 Wei Li ，Ping Liu ，Yonghua Rong ，Fengcang Ma ，Xinkuan Liu (1. School of Materials Science and Engineering, University of Shanghai for Science and Technology, Shanghai, 200093, China； 2. School of Materials Science and Engineering, Shanghai Jiao Tong University, Shanghai, 200240, China) Abstract: A nanocrystalline surface layer was produced in Ni plate by surface mechanical attrition treatment (SMAT). The characterization of microstructure and composition indicates that foreign elements from hardened balls, such as Fe, can diffuse and permeate into the surface layer during SMAT, which can further diffuse and homogenize in the surface layer when annealing at high temperature, leading to formation of new alloy. The formation of new alloy leads to the different magnetic property of Ni plate, and the result shows that the value of Curie temperature (T ) for nanocrystalline Ni surface c layer induced by SMAT can exceed 600℃, much higher than that for