B10在模拟海水中的冲刷腐蚀研究.pdfVIP

The 6th China Corrosion Conference Erosion-Corrosion of 90/10 Cu-Ni Alloy in Artificial Seawater Chengjun YIN, Guozhe MENG, Tao ZHANG, Yawei SHAO College of Materials Science and Chemical Engineering, Harbin Engineering University, Harbin 150001 Email : chengjun6725@163.com, mengguozhe@ Abstract: In this paper, a set of jet apparatus was used to simulate the erosion-corrosion of 90/10 cop- per-nickel alloy in artificial seawater. Potentiodynamic polarization curves and electrochemical impedance spectroscopy (EIS) were employed to study the electrochemical corrosion behavior of the sample at different impact velocity (0m/s, 3m/s and 6m/s) and different impact angles (0°, 30°, 45°, 60° and 90°). The results show that the impedance of the sample in static seawater and flowing seawater are gradually increased with the increasing time. EIS displays a high-frequency capacitive impedance and a low-frequency diffusive im- pedance in static seawater, a high-frequency capacitive impedance and a low-frequency real constriction im- pedance in flowing seawater. At a flow rate of 3m/s, the impedance modulus increased with the increasing impact angle. At the flow rate of 6m/s and the time of 1h, the maximum impedance modulus are gained at the impact angles of 30°. The minimum impedance modulus can obtain in the impact angles of 30° as the time increase. With the flow velocity increasing, the impedance decreases gradually. Keywords: 90/10 copper-nickel alloy; erosion-corrosion; impact velocity; impact angle B10 在模拟海水中的冲刷腐蚀研究 尹承军，孟国哲，张涛，邵亚薇 哈尔滨工程大学材料科学与化学工程学院，哈尔滨，150001 Email