利用煤矸石制备4A沸石的动力学模型.pdfVIP

19 1 Vol. 19 No. 1 2009 1 Journal ofHeilongjiang Institute of Science Technology Jan. 2009 : 16 1- 0118( 2009) 01- 0001- 04 4 A 秦 华, 袁丽艳, 汪 洋 ( , 15002 ) : 为研究煤矸石合成 4A 沸石的制备理论, 以依兰矿区煤矸石为原料, 在最佳 应条件 下, 对不同 应时间内产品的结晶度进行了实验分析, 依据待定系数法, 整合动力学方程, 最终得到 利用煤矸石制备 4A 沸石的动力学模型, 并将模型方程与实验晶化曲线拟合结果表明: 4A 沸石 结晶 应发生在凝胶后期; 在晶化后期, 凝胶溶解速率决定了晶体生长速率和有限晶化时间内产品 结晶度的大小; 动力学实验数据与模型曲线有较好的吻合 : 煤矸石; 4A 沸石; XRD; 动力学模型 : TQ424. 25 : A Dynam ic equations o f 4A zeo lite synthes ized by gangue QIN Hua, YUAN Liyan, WANG Yang ( College of Resource and Environm en t Engineerring, H eilongjiang Institute of Science and Technology, H arbin 15002 , Ch ina) Abstract: In order to study a theory of synthesism ethod of 4A zeolite synthesized by gangue, exper-i mental analysis of crystallization degree of the products at themost su itable conditions w as accqu ired by using gangue in Y ilan as raw materials, and the products w ere made in different expermi ental tmi e. By means of undeterm ined coefficientmethod, the dynam ic equationsw eremerged and the dynam icmodel of synthesizing 4A zeolite by gangue w ere acqu ired. The model of equations and the crystallization curve of expermi entw ere fitted. The resu lts show that the crystallization form ation of 4A zeolite occurs in the ana- phase of gel. The dissolving rate of gel determ ines the grow ing rate of crystal and the level of crystalliza- tion degree during a lmi it period in the anaphase of crystallization. The resu lts of dynam ic expermi ent are almost equal