溶胶—凝胶法制备的ZrO2涂层对低碳钢腐蚀的保护.pdfVIP

第 14 卷 第 2 期 腐蚀科学与防护技术 Vol 14 No2 2002 年 3 月 　　　　 　　　　 Mar 2002 CORROSION SCIENCE AND PROTECTION TECHNOLOGY 溶胶 - 凝胶法制备的 ZrO2 涂层对低碳钢腐蚀的防护 李海滨 　梁开明　梅乐夫　顾守仁 ( 清华大学材料科学与工程系 北京 100084) 摘要 　采用溶胶 - 凝胶法在基板上涂覆了 ZrO2 涂层. 通过 XRD 和 SEM 研究了热处理温度对涂层相结构和形貌 的影响 ,采用动电位极化曲线评估了涂覆样品的电化学腐蚀行为 , 并与原始样进行了比较. 结果显示 ,800 ℃和 400 ℃热处理的涂层有好的耐腐蚀性能 ,并分别提高低碳钢基板的寿命 63 和 2 4 倍 ;相反 ,600 ℃热处理的涂层 , 对基板没有腐蚀防护作用. 关键词 　ZrO2 　溶胶 —凝胶涂层 　腐蚀防护 　低碳钢 中图分类号 　17421 　　文献标识码 　A 　　文章编号 (2002) CORROSION PROTECTION OF MILD STEEL BY SOL - GEL ZIRCONIA COATINGS L I Haibin ,L IAN G Kaiming ,MEI Lefu , GU Shouren ( ) Depart ment of M aterials Science and Engineering , Tsinghua U niversity , Beijin g 100084 ABSTRACT 　Zirconia coatings were deposited on mild steel by sol - gel method. The temperature de pendence on phase structure and morpholo gy of coatings were investigated by X - ray diffraction ( XRD) and scanning electron microscope ( SEM) . The electrochemical corrosion of mild steel was eval uated through potentiodynamic polarization curves without and with zirconia coatings. The results show that the coatings heat - treated at 800 and 400 ℃for 1h have good corrosion resistance ,and increase the life time of the mild steel by a factor of 6. 3 and 2. 4 ,respectively. In contrast ,the coating obtained at 600 ℃have no positive effect on the corrosion resistance of the substrate. KEY WORDS 　zirconia ,sol - gel coatings ,corrosion protection ,mild steel