等离子喷涂纳米硫化物涂层的显微结构与摩擦学性能研究.pdf

摘要 的粉末颗粒尺寸在20～80um，流动性好，适合于等离子喷涂。利用等离子喷涂技术制备了纳米 术对涂层的物相组成、显微结构及成分进行了表征。实验结果表明：纳米FeS涂层的物相主要为 层的孔隙率大约为19％：纳米一噩微米MoS2涂层的物相主要为六方的MoS2，还有少量的Mo， 融的纳米颗粒的重结晶和夹杂于涂层中的未熔融的纳米颗粒。摩擦磨损实验表明：在油润滑I手¨于 摩擦两种条件下，纳米FeS涂层的减摩耐磨性与GCrl5钢原始表面相比，均有了明显的提高，尤 其在油润滑条件下，摩擦系数降低1倍，在商载条件下，磨损量也降低近1倍；油润滑条件F， 纳米一亚微米MoS2涂层的减摩耐磨性与GCrl5钢原始表砸相比，摩擦系数降低近1倍，在高载 条件下．磨损量也降低近l倍。 含量越多，涂层表面越粗糙，表层结构越疏松。当SiC含量为20％时，涂层的摩擦系数和磨损枣 均最低，涂层的减摩耐磨性最好。 关键词：等离子喷涂；纳米结构：硫化物涂层；摩擦磨损 Abstract Nanoseale were mechanical FeS、FeS—SiC、MoStpowders preparedby milling．Beforespraying， the werereconsitituedtoform from20to80umwithexcellent powers granulesranging flowability andweresuitablefor FeS FeS·SiC plasmasprayingprocess．Nanostructured coating，nanostructured andnano-andsubmicmn—structuredwere compositecoating coatingdepositedbyatmosphericplasma and microstructure ofthe WerecharacterizedwithSEMand spraying．The phasecompositioncoatings WaSfound FeS that：thenanostructuredWas of FeS，a XRD，respectively．It coatingmainlycomposed small of andoxidewerealsofound．Thesizeofthe WaS 50～100nm；the quantityFel．xS grain coating nanostrueturedFeS—SiC exhibitedabimodaldistributionwithsmall plasma-sprayed compositecoating Was ofFeSandSiC，a grains(30—80nm)andlargegrains(100—200nto)．Thecoatingmainlycomposed small