X-射线原位研究外场作用下生物降解高分子材料的结构形成与转变.pdfVIP

X-射线原位研究外场作用下生物降解高分子材料 的结构形成与转变 熊祖江1刘国明1文韬1张秀芹2王笃金1 1中国科学院化学研究所，北京 100190 2北京服装学院材料科学与工程系，北京 100029 可规模化生产的生物降解高分子材料的应用领域不断扩大，有关其成型过程中的凝聚态 结构形成和使用过程 （服役行为）中的结构转变与失效也逐渐引起人们的关注1-2。本文以聚 乳酸 (PLA)和聚丁二酸丁二醇酯(PBS)这两类常见生物降解高分子材料为对象，用DSC 和WAXS/SAXS等方法综合考察了其在结晶/熔融和拉伸形变过程中的结构形成与转变，阐明 了在升降温过程中PLLA/PDLA立构复合晶(sc-crystal)形成与结构转变的基本问题，探讨了 PBS在拉伸过程中的片晶增厚机理，深化了对PLA和PBS凝聚态结构特点的认识。 In-situX-raystudyonthestructureformationandevolutionof biodegradablepolymersunderexternalfields XIONGZujiang1LIUGuoming1WENTao1ZHANGXiuqin2WANGDujin1 1.InstituteofChemistry,theChineseAcademyofSciences,Beijing100190;Departmentof MaterialsScienceEngineering,BeijingInstituteofFashionTechnology,Beijing100029 Abstract:weinvestigatedthedynamicformationandtransitionofsc-crystalsinPLLA/PDLA drawnfilmwithacombinationofin-situsynchrotronwide-angleX-rayscattering(WAXS), small-angleX-rayscattering(SAXS)anddifferentialscanningcalorimetry(DSC).Thecorrelation betweensc-crystalscontentandthecompetingformationofα crystalsinhomopolymersduring continuousheatingandcoolingprocesseswasalsostudied.Itwasfoundthatatroomtemperature, theoriginalPLLA/PDLAdrawnfilmconsistedofonly α crystals,however,withtemperature increasing,twopopulationsofsc-crystalswereformedatdifferenttemperaturesfromtheoriented amorphousregionandthemoltenα crystalsinthehighly-orientedsample,respectively. Furthermore,newtypesofsc-crystalsand αcrystalswiththeorientationperpendiculartothe originalsc-crystalswereformedduringsubsequentcoolingprocess.OnthebasisoftheX-ray scatteringandDSCdata,aschematicmodelforcrystallizationandorientedvariationconcerning sc-crystalsandα crystalswasproposed.Forpoly(butylenesuccinate)(PBS),thecrystaltransition wasobservedduringtensiledeformationat30-90℃.Anincreaseoflongperiodwasidentified duringstretchingthePBS.Thestep-cycledeformationmeasurementshowedthatthelongperiodL reversiblyincr