填充复合型导电高分子材料导电机理及导电性能影响因素研究概况.pdfVIP

36 11 Vo l36 No11 2008 11 N EW CH EM ICAL M A T ERIA L S 13 叶明泉 贺丽丽 韩爱军 ( 南京理工大学化工学院, 南京210094) 采用渗流理论量子力学隧道效应理论和场致 射效应等理论, 对填充复合型导电高分子材料的导电机理 进行了分析介绍; 从聚合物的结构导电填料的种类性能用量复合材料制备方法加工及使用条件等因素, 分析了影响 填充复合型导电高分子材料导电性能的主要因素 填充, 导电高分子材料, 导电机理, 渗流, 量子力学隧道效应, 场致 射 Conductivity mechanism and electrical properties inf luence f actors of f illing conductive polymer composite materials Y e M ng quan H e L l H an A jun ( School of Chem cal Eng neer ng , N anj ng U n vers ty of Sc ence T echnolo gy, N anj ng, 210094) Abstract T he conduct v ty mechan sm of f ll ng conduct v e polymer compos te mater als w as ntroduced by u s ng theo r es o f perco lat on , quant um mechan cs tunnel ng eff ect and f eld em ss on . T he st ructur e o f polymer , the k nds, char acter st cs, and do sages o f conduct v e f llers, prepa r ng, pr ocess ng and apply ng co nd t ons of compos te mat er als w ere t he most mpor tant f acto rs w h ch aff ect the electro conduct v ty of f ll ng conduct v e polymer compos tes, the eff ects of above f act ors w ere presented . Key words f ll ng , conduct ve po ly mer mater al, co nduct v t y mechan sm , perco lat o n, quantum mechan cs tunne l ng eff ect , f eld em ss on , , ; , , ( ) , , , 10 , :