高质量分数对二甲苯结晶动力学研究_陈亮.pdfVIP

37 10 V o l. 37 N o. 10 2009 10 CHEM ICAL ENG INEER ING ( CH INA ) O ct. 2009 1 1 1 2 陈 亮, 肖 剑 , 谢在库 , 于建国 ( 1. , 201208; 2. , 200237) : , , , , , , , ? 0. 5% , : ; ; ; : TQ 026. 7; TQ 241. 1 : A : 1005-9954 ( 2009) 10-0022-0 3 Crystallization kinetics ofp -xylenewith highmass fraction 1 1 1 2 CHEN Liang, XIAO Jian , XIE a-iku, YU Jian-guo ( 1. SINOPEC Shangha Research Inst tute of P etrochem cal T echno logy, Shangha 201208, Ch na; 2. State Key Laboratory o f Chem cal Eng neer ng, E ast Ch na Un vers ty of Sc ence and T echno logy, Shangha 200237, Ch na) Abstract:T he crysta ll zat on k net cs o f p-xy lene n p-xy lene-r ch m xed xy lenes w as stud ed by unseeded batch coo l ng crystall zat on experm ents. The popu lat on ba lance equat on w as so lved w th the m ethod of m om ents. In each experm ental run, the tem perature of m other l qu d and m ass fract on ofp-xy lene w ere traced and recorded as tm e elap sed. T he crysta ll zat on k net cs param eters w ere ob ta ned w th nonl near optm zat on m ethod. T he experm ental resu lt show s that the crystall za t on k net cs param eters obta ned under the natural cool ng pro f le and l near coo l ng prof le are n good agreem ent. The calcu lated concentrat on of m other l qu d w th these crystall zat on k net cs param eters are n good co nc dence w th the experm entalm easured concentrat on n all cases. M ost re la t ve errors fall nto the bound of ? 0. 5% . T hese crystall zat on k