CuO-Ce1-xZrxO2催化剂的制备及其VOC催化燃烧性能研究【毕业论文】.doc

本科毕业论文 （20 届） CuO-Ce1-xZrxO2催化剂的制备及其VOC催化燃烧性能研究 专业：化学工程与工艺 [摘要]本文研究CuO-Ce-ZrO2催化剂在VOCs中的性能。在先考查CuO-CeO2催化剂的性能基础上，再考察CuO-Ce-ZrO2催化剂的性能。采用柠檬酸络合法共沉淀法CuO-Ce1-xZrxO2 Catalyst preparation and VOC catalytic combustion performance study [Abstract] In this paper, CuO-Ce-ZrO2 catalysts in the performance of VOCs. Earlier examined the performance of CuO-CeO2 catalysts based on, and then examine CuO-Ce-ZrO2 Catalysts. Use of citric acid by the cerium nitrate solution of copper nitrate and zirconium nitrate mixed Moore (Ce + Cu + Zr): citric acid = 1.2:1 mixture of citric acid at room temperature and stir for 1 hour; water bath at 70 ℃ thermostatic mixing evaporated to gel; incubator at 80 ℃ for 12 hours drying; in self-propagating combustion, calcination at 400 ℃ for 4 hours. Co-precipitation of cerium nitrate is copper nitrate mixed solution of zirconium nitrate and Na2CO3: NaOH = 1:1 mixed solution at PH = 10 under the titration completely, stirring 4 hours at room temperature, put it aside overnight, then the filtration, with distilled water repeatedly washed 2 to 3 times, drain and put into 80 ℃ oven drying for 12 hours, and finally into the furnace and fired 4 hours. Impregnation method was obtained by co-precipitation method CeO-ZrO vector, and impregnated with Cu, soaking overnight, into the oven 12 hours, the final baking for 4 hours. From the three catalysts, the best activity is citric acid, and then to prepare the catalyst calcination temperature. The effects of different temperatures on the catalytic activity. And the use of XRD, H2-TPR, BET and other methods to make a detailed characterization of the catalysts. Keywords: CuO-Ce-ZrO2 catalysts；Catalytic combustion；Citric acid winding legal；XRD  中文摘要 I 英文摘要 II 1 前言 1 1.1、VOC催化燃烧特性 1 1.1.1、催化燃烧的基本流程 1 1.1.2、VOC催化燃烧特点 2 1.2、催化剂 2 1.2.1催化剂种类 2 1.2.2、催化剂的制备方法 3 1.3本论文研究目的、思路、内容 4 1.3.1本课题的研究目的和思路 4 1.3.2本文工作 4 2 实验部分 5 2.1 催化剂的制备 5 2.1.1 化学试剂 5 2.1.2设备介绍 5 2.2 催化剂表征 6 2.2.1 X射线衍射仪（XRD） 6 2.2.2 静态氮吸附仪（BET） 7 2.2.3