Ni-CeO2催化剂VOCs催化燃烧性能研究【毕业论文】.docVIP

本科毕业论文 （20 届） Ni-CeO2催化剂VOCs催化燃烧性能研究 专业：化学工程与工艺 [摘要]VOCs有机废气主要来自于化工生产、制药等行业，废气中带有恶臭，并且会对人体造成伤害，甚至会导致中毒、致癌、致突变。而催化剂是催化燃烧法消除VOCs的关键技术，所以用共沉淀法、浸渍法、沉积沉淀法和柠檬酸络合法制备出Ni含量分别为5%、10%、15%、20%的Ni-CeO2催化剂，并用XRD、TPR、BET、活性检测等方法对其进行详细的表征。 实验研究结果表明制备方法对催化剂活性和催化剂的氧化还原性质影响较大。共沉淀法制备的催化剂活性最好，催化剂中有较多的Ni2+进入CeO2晶格，其余高分散在载体表面。而沉积沉淀法、浸渍法和柠檬酸络合法制备的催化剂活性较低，CeO2载体很难形成氧空位，在催化剂中Ni大都以大颗粒NiO形式聚集在催化剂表面。由此可见，催化剂中氧空位和高分散的Ni，有利于催化燃烧反应的进行；但当催化剂中缺少氧空位以及高分散的Ni过多时都会会导致催化剂的活性下降。 关键词：催化燃烧；Ni-CeO2催化剂；氧空位；XRD；BET；TPR Ni-CeO2 catalyst for catalytic combustion of VOCs [Abstract] VOCs volatile organic compounds mainly from chemical production, pharmaceutical and other industries, with the stench of exhaust, and harm to human body and even lead poisoning, carcinogenic, mutagenic. The catalyst is the key of catalytic combustion method to eliminate VOCs. In this paper coprecipitation, impregnation, deposition-precipitation and sol-gel methods were used to prepared Ni-CeO2 catalysts with Ni content from 5% to 20%. The Ni-CeO2 catalyst activity for catalytic combustion of VOCs had been detected. The catalysts were characterized with XRD, TPR, BET method. Experimental results show that the preparation method influenced the redox properties and catalytic activity. The catalyst prepared by coprecipitation method has the best activity. In the catalyst, there is more Ni2 + into the CeO2 lattice, and the remaining highly dispersed on the support surface. The catalysts prepared by deposition-precipitation, impregnation and sol-gel method have lower activity. In these catalysts, CeO2 lattice is difficult to form oxygen vacancies, Ni mostly present in the form of large NiO particles gather on the catalyst surface. Thus, the catalyst of oxygen vacancies and high dispersion of Ni, is conducive to the catalytic combustion reaction; but the lack of oxygen vacancies in the catalyst and high dispersion of Ni will lead to excessive activity of the catalyst decreased. Keywords: catalytic combustion; Ni-CeO2 catalyst; Oxygen vac