SDBS与HA缓蚀剂复配实验与理论研究.pdf

物理化学学报(Wuli Huaxue Xuebao) February Acta Phys. ⁃Chim. Sin. 2011, 27 (2), 275-280 275 [Article] SDBS 与HA 缓蚀剂复配的实验与理论研究 胡松青 于立军 燕友果* 张 军 任振甲 提 阳 ( 中国石油大学物理科学与技术学院, 山东东营257061) 摘要: 通过静态失重法研究了十二烷基苯磺酸钠(SDBS)与六亚甲基四胺(HA)在盐酸溶液中对Q235 钢的协 同缓蚀效应, 并采用分子动力学模拟从缓蚀剂膜抑制腐蚀粒子扩散的角度对其缓蚀机理进行分析. 结果显示: SDBS 和HA 单独使用时, 最高缓蚀效率分别为82.82%和79.46%, 复配后最高缓蚀效率可达到92.78%; 与两 种缓蚀剂单独使用时相比, SDBS 与HA 复配后缓蚀剂膜体系中的自由空间明显下降, 削弱了膜内缓蚀剂分子 的自扩散能力, 腐蚀粒子在缓蚀剂膜携带下的被动迁移也随之减弱; SDBS 与HA 复配能更有效抑制腐蚀粒子 在缓蚀剂膜中的扩散, 也就是说复配后的缓蚀剂具有更好的缓蚀性能. 关键词: 十二烷基苯磺酸钠; 六亚甲基四胺; 失重法; 分子动力学模拟; 扩散系数 中图分类号: O642; O646; TG 174.42 Experimental and Theoretical Study of the Synergistic Inhibitive Effect of SDBS and HA HU Song-Qing YU Li-Jun YAN You-Guo* ZHANG Jun REN Zhen-Jia TI Yang (College of Physics Science and Technology, China University of Petroleum, Dongying 257061, Shandong Province, P. R. China) Abstract: The synergistic inhibitive effect of sodium dodecylbenzene sulfonate (SDBS) and hexamethylene tetramine (HA) toward Q235 steel in hydrochloric acid was investigated by the static weight loss method. We also studied the inhibition mechanism by molecular dynamics simulations with regard to the inhibition of aggressive particle diffusion by inhibitor membranes. SDBS and HA were found to have individual inhibition efficiencies of 82.82% and 79.46%, respectively. These inhibition efficiencies increased to an efficiency of 92.78% when SDBS and HA were combined.