MBR复合工艺膜污染及其清洗特征.pdfVIP

19 2 V ol. 19No. 2 2009 6 JOU RNA L OF EM CC Jun2009 10. 3969/ . issn. 1008- 813X . 2009. 02 . 015 M BR 复合工艺膜污染及其清洗特征 杨继贤 ( 兖矿集团环保节能处, 山东 邹城 273500) : 采用A + ( A/ O) n+ M BR复合工艺, 在次临界通量条件下, 考察了 污染发展及清 洗特性试验发现, 污染随运行时间的变化呈现出阶段性上升的特征, 即经过初期缓慢发展 和中期较快发展后, 出现了 污染的急剧增加电镜及能谱分析表明, 面污染物主要包括沉 积于 面的大量污泥絮体附着于 面的致密凝胶层和一些由Ca2+ M g2+ 等离子形成的堵塞 和吸附于 孔的无机垢粒 清洗及阻力表明, 自来水冲洗可使泥饼层大部分脱落, 泥饼层对 污染阻力贡献最大, 达到60. 7 1% ; N aClO 清洗对凝胶层的去除效果显著, 有机污染对 污 染阻力为31. 44% ; H Cl 清洗去除的无机垢粒对 污染贡献率仅为7. 85% : M BR 复合工艺; 污染; 扫描电镜; 阻力分析 : X 505 : A : 100 8- 8 13( 2009) 02- 0046- 04 Characteristic of Fouling and Cleaning of MBR Hybrid Process Y ang Jixian ( D ep art ment of E nv i ronmental Pr otec ti on and Energ y Conser v ation , Yankuang Gr oup , Zouche ng Shandong 237500) Abstract: Charact erist ic of membrane fo uling development and cleaning in an A + ( A/ O) n+ MBR pro cess w as invest ig at ed under the condit io n of sub- cr it ical flux . It co uld be concluded that a charact erist ic t hree- st age t rans- m em brane pressure( T M P) pro file w as observed w it h an init ially ext ended period o f slow and fast T M P rise f ollo wed by a sudden t ransit ion t o a rapid rise. Fr om SEM examinatio n, it w as fo und t hat contaminant s att ached on t he m em- brane surf ace co mpr ised lar ge am ount sludge flcc and g el layer f orm ed by fine part icles and macro- mo lecular org anic subst ance, especially EPS, and som e inorgan