氮掺碳纳米管载铂催化剂的制备及表征.docVIP

氮掺碳纳米管载铂催化剂的制备及表征 作者：金祥 摘 要：本实验通过氮的掺杂方式，开发催化剂的新结构等方面入手，改进了催化剂的电催化性能，并通过傅里叶变换红外光谱（FTIR）、拉曼光谱（Raman）、元素分析、热重分析仪（TGA）、透射电子显微镜（TEM）等分析测试技术，详细研究了催化剂的形貌、结构等，CNTs-PDA由多巴胺包裹CNTs在高温碳化的条件下自发聚合而制备出N掺杂的CNTs（N@CNTs），催化剂则在N@CNTs为载体的条件下由乙二醇还原后负载Pt制备得到。将产品CNTs-PDA用TGA和FTIR表征，用Raman对高温碳化得到的N@CNTs进行表征，Pt/N@CNTs催化剂的形貌特征用TEM观察。结果表明，最终产物N@CNTs具有含N量高、分布均匀的碳层，并能在上面制备出高分散、小颗粒尺寸的Pt NPs。 关键词：多巴胺 氮掺杂碳管 Preparation and Characterization of Carbon Nanotubes doped with Nitrogen supported Platinum Nanoparticles Abstract: The methods of nitrogen doped and new structure of classical catalysts were developed and studied in this experiment. Characteristic of the catalysts had been developed. the structure of catalysts are studied by Fourier transform infrared spectroscopy(FTIR),Raman spectroscopy(Raman),elemental analysis, thermogravimetric analysis (TGA), transmission electron microscopy (TEM) and other analytical techniques. Catalyst are studied in detail to appearance and structure.CNTs wrapped with Dopamine surface at high temperature carbonization conditions and with spontaneous polymerization to prepare N-doped CNTs (N@CNTs), and the catalyst which was prepared using N@CNTs as carrier and Pt carried by the ethylene glycol. The N@CNTs was analyzed by FTIR and TGA, and N@CNTs characterized with Raman spectroscopy and Pt / N@CNTs catalyst used TEM observation. Result showed that N@CNTs having a final product containing high nitrogen, and evenly the carbon distributed uniformly , high dispersion and small particle size Pt NPs can be prepared. Key words：Dopamine Nitrogen-doped Carbon nanotubes0 前言 碳纳米管（CNTs）作为最理想的一维纳米材料，由于其机械强度优异、化学稳定性好和好的电子导体等优点引起了相关学科研究人员的广泛关注[1-3]，并被广泛用于电子设备、量子线、高强度材料、生物传感器和催化剂载体等领域[4,5]。迄今，科研工作者在应用CNTs之前，通常要先对其进行表面修饰。特别是在燃料电池研究领域，CNTs作为燃料电池催化剂载体负载贵金属纳米粒子（NPs），其催化效率远远高于无载体的纯纳米金属材料的催化效率。而在实际研究中，通常要求NPs以较小的粒径在CNTs表面高度分散，这样才能获得经济、高效的催化剂[6]。但是CNTs表面缺陷少、缺乏活性基团，表面呈化学惰性，这造成NPs与CNTs结合力弱，且颗粒尺寸大、分散性差[7-9]。因此，对CNTs表面修饰以期达到与NPs最优结合是当前燃料电池催化剂的研究热点之一。 目前对于CNTs的修饰主要是集中在两个方面：（1）功