均匀沉淀法合成Co2FeO4粉料.docVIP

均匀沉淀法合成Co2FeO4粉料 作者:金祥 摘 要：本试验以分析纯CoSO4·6H2O 和分析纯FeCl3·6H2O为主要原料， NaOH溶液为沉淀剂，采用均匀沉淀法合成Co2FeO4粉料，在800 ℃温度下煅烧2.5小时用激光颗粒测量分布仪测定产物粒径尺度，热重分析仪分析产物热稳定性，XRD分析产物衍射图谱，透射偏光显微镜测定产物晶体形貌。试验结果表明，Co2FeO4粉料粒径分布窄、分散性好、热稳定性好、晶体形貌均一、颗粒尺寸小且平均粒径分布在0.50~ 2.00 μm之间。用均匀沉淀法制备Co2FeO4粉料比传统的制备方法具有试验材料易得，对技术和设备要求不高，反应可控等优势Synthesis of Co2FeO4 powder by Homogeneous precipitation method Abstract：his test ,with analytical reagent CoSO4 · 6 H2O and analytical reagent FeCl3 · 6 H2O as the main raw material and NaOH solution as precipitant,Co2FeO4 powder was synthesized by homogeneous precipitation.Calcining the product about 2.0 hours at 800 ℃,and its particle size was measured by laser particle distribution measuring instrument, and thermogravimetric analyzer analyzed thermal stability,and XRD diffraction analyzed diffraction spectrum, and transmission polarizing microscope determined crystal morphology.The test results showed that Co2FeO4 powder particle size distributed narrowly, had good dispersibility and thermal stability,and uniform crystalline morphology,and its particle size was small and the average particle size distributed between 0.50 ~ 2.00 um. Preparing Co2FeO4 powder with homogeneous precipitation compared with traditional preparation.Test materials were readily available. The requirements on technology and equipment was not strict.The reaction was controllable.And there were other advantage. Key words：Co2FeO4 powder XRD size?distribution precipitator 0 前言 铁酸钴粉料是一种性能优良的磁性材料具有高饱和磁化强度和矫顽力、大的磁晶各向异性和磁性伸缩性，良好的化学稳定性，是一种很好的磁性记录和磁光记录材料。同时，文献报道铁氧体Co2FeO4粉料有着良好的催化性、耐候性、耐光性、磁性和对紫外线具有良好的吸收和屏蔽效应，可广泛应用于闪光涂料、油墨、塑料、皮革、汽车、面漆、电子、高磁记录材料、催化剂以及生物医药、航天航空、国防军事等方面，所以了解和掌握铁氧体粉料的制备方法无疑具有重要的现实意义。近年来，大量实验表明：材料的晶粒尺寸越小达到微米级甚至是纳米级时，除了呈现一些异常的电学、磁学等性质，还可以提高其烧结活性。因此，铁氧体粉料的合成是当前材料研究热点之一，世界各国无论是西方发达国家还是发展中国家都积极培养科研人才加大资金投入，研究具有高性能的铁氧体粉料的合成方法。 铁氧体粉料的制备方法和制备技术直接决定了铁氧体粉料的性能，从而进一步影响到器件的性能和经济效益。铁氧体粉料的方法总体上可以湿法和干法，湿法多以工业绿矾、工业氧化铁或硝酸铁等为原料，采用水热法、均匀沉