酸-碱交替沉淀法制备铜基甲醇合成催化剂地研究.pdfVIP

酸-碱交替沉淀法制备铜基甲醇合成催化剂的研究 岑亚青，李小年，刘化章* （浙江工业大学催化研究所，绿色化学合成技术国家重点实验室培育基地，浙江杭州 310032 ） 摘 要 采用酸-碱交替沉淀法制备了一种新型的低压甲醇合成催化剂。研究了pH值对催化剂性能的影响。结果表明， pH值交替范围为5.0-9.5制备的催化剂活性最好。与其它不同制备方法相比，酸-碱交替沉淀法制备的催化剂具有最高 的活性和耐热性，耐热后活性保留率达88%，比其它催化剂高8-20%，而且耐热后活性还高于其它催化剂的初活性。 采用酸-碱交替沉淀法明显提高了催化剂的活性和耐热性。XRD 、SEM等研究结果表明，酸-碱交替沉淀法制备的催化 剂的XRD谱线中铜锌的特征峰最为宽化、弥散；催化剂的粒度较小，分布较均匀，结晶度相对较低。 关键词 甲醇合成，铜基催化剂，酸-碱交替沉淀法，pH 值，制备方法 中图分类号 O 643 文献标识码 A Preparation of Copper-based Catalysts for Methanol Synthesis by Precipitation Method of Alteration between Acid and Alkali CEN Yaqing, LI Xiaonian and LIU Huazhang* (Institute of Industrial Catalysis, State Key Laboratory Breeding Base of Green Chemistry Synthesis Technology, Zhejiang University of Technology, Hangzhou, 310032, Zhejiang, China) Abstract: A new catalyst for methanol synthesis was prepared by precipitation method of alteration between acid and alkali. It was found that when the range of pH value was from 5.0 to 9.5, the activity of catalyst was the best. Compared the activity and thermal stability of catalysts which prepared different methods, it was found the activity and thermal stability of catalyst which prepared by precipitation method of alteration between acid and alkali was the best. The hold rate of activity after thermal test of this catalyst was 88%, which was higher than other catalysts 8-20%. Furthermore, the activity of this catalyst after thermal test was higher than the activity of other catalysts before thermal test. Using this method, the activity and thermal stability of the catalyst could be increased obviously. The catalysts were characterized by the means of XRD and SEM. From XRD pattern, it was shown that the characteristic peak of CuO and ZnO were far more dispersed in the catalyst prepared by precipitation method of alteration between acid and alkali. From SEM