电沉积制备ZnO纳米棒修饰电极上氧化还原蛋白的电化学行为.pdfVIP

物理化学学报 Wuli Huaxue Xuebao 468 Acta Phys. ?Chim. Sin. 2011, 27 2 , 468-472 February [Article] 电沉积制备ZnO 纳米棒修饰电极上氧化还原蛋白的电化学行为 韩楠楠2 王 慧2 栗 娜2 周剑章1, 2,* 林仲华1,2 吴 迪3 万国江3,* 1 2 厦门大学固体表面物理化学国家重点实验室, 福建厦门361005; 厦门大学化学化工学院化学系, 福建厦门361005; 3 西南交通大学材料科学与工程学院, 成都610031 摘要: 采用恒电位阴极还原法在金电极表面一步修饰ZnO 纳米棒, 制备成ZnO 纳米棒修饰电极. 扫描电子显 微镜 SEM 和X 射线衍射 XRD 结果显示制得的ZnO 为直径约100 nm 的六棱柱状纤锌矿晶体纳米棒. 使用 ZnO 纳米棒修饰的金电极研究细胞色素c 的直接电化学行为, 结果表明: ZnO 纳米棒修饰的金电极能有效探测 到细胞色素c 的铁卟啉辅基在不同价态下的电化学行为; 细胞色素c 吸附后, ZnO 纳米棒修饰的金电极对过氧 化氢的电流响应呈现良好的线性关系. 关键词: ZnO 纳米棒; 电沉积; 氧化还原蛋白; 细胞色素c 中图分类号: O646 Electrochemical Behavior of Redox Proteins on ZnO Nanorod-Modified Electrodes Prepared by Electrodeposition 2 2 2 1, 2,* 1, 2 HAN Nan-Nan WANG Hui LI Na ZHOU Jian-Zhang LIN Zhong-Hua WU Di3 WAN Guo-Jiang3,* 1 State Key Laboratory of Physical Chemistry of the Solid Surface, Xiamen University, Xiamen 361005, Fujian Province, P. R. China; 2Department of Chemistry, College of Chemical Engineering, Xiamen University, Xiamen 361005, Fujian Province, P. R. China ; 3School of Materials Science and Engineering, Southwest Jiaotong University, Chengdu 610031, P. R. China Abstract: We successfully prepared ZnO nanorod-modified Au ZnO nanorod/Au electrodes using one-step cathodic electrodeposition. Scanning electron microscopy SEM and X-ray diffraction XRD were used to characterize the morphology and crystal phase of the ZnO nanorods. The data showed that the ZnO nanorods were wurtzite type crystals with a hexagonal rod shape and a diameter of about 100 nm and that the ZnO nanorods were arranged well on the surface of electrodes. These ZnO nanorod-modified electrodes were able to detect direct electron transfer from cytochrome c cyt c . Cyclic voltammograms showed that the direct electron transfer of cyt c with heme iron in different valence states was easily achieved by the ZnO nanorod/Au electrode. Data of amperometric responses demonstrated that a linear