超声场对钛溶胶及材料微结构的影响.pdfVIP

超声场对钛溶胶及其材料微结构的影响* 1 1 1 1 董仲美 ，曹雪萍 ，景文珩 ，邢卫红 （1 南京工业大学化学化工学院材料化学重点实验室, 江苏，南京，210009 ） 摘要：本文采用超声溶胶-凝胶法，以钛酸四丁酯为前驱体，乙酰丙酮为螯合剂，硝酸为催化剂，利用超 声空化效应制备颗粒粒径小且分布窄的TiO2 溶胶，考察了超声时间和超声功率对TiO2 溶胶及材料的微结 构性质的影响。采用流变仪、粒径分析仪、XRD 、低温N2 吸附-脱附等手段对溶胶及材料进行了系统表征。 结果表明：随着超声时间和超声功率的增大，溶胶粒径逐渐变小，而对溶胶的粘度影响不大，溶胶稳定性 较好；且随着超声时间和超声功率的增大，制备的TiO2 材料的孔容和比表面积逐渐增加，晶粒尺寸逐渐 减小，TiO2 材料主要为锐钛矿相。因此，将超声溶胶-凝胶法应用于制备小孔径二氧化钛超滤膜具有良好 的应用前景。 关键词：超声场；溶胶-凝胶法；二氧化钛 Influence of ultrasonic field on titanium sol property and material microstructure 1 1 1 1 Dong Zhongmei , Cao Xueping , Jing Wenheng , Xing Weihong 1 ( State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemistry and Chemical Engineering, Nanjing University of Technology, Nanjing 210009, China) Abstract ：In this paper, titanium sols with small particle size and narrow particle size distribution can be obtained by ultrasonic sol-gel method, using tetrabutyl titanate as precursor, acetylacetone as chelating agent, 1-butanol as solvent, and nitric acid as catalyst. And we investigated the influences of ultrasonic irradiation time and ultrasonic power on titanium sols and the microstructure of titania materials. Rheometer, particle analyzer, X-ray diffraction and low temperature N2 adsorption-desorption, SEM techniques were used to analyse the viscosity and particle size of the titania sol and the microstructure of titania materials systematically. It showed that the diameter of sols became smaller, but the viscosity of titania sol changed very little under different ultrasound condit