水热炭基铀选择性固相萃取剂的合成.docVIP

水热炭基铀选择性固相萃取剂的合成 宋强，马利建，刘军，白翅遥，耿俊霞，王航，李首建* 四川大学化学学院，成都，610064 *Email: sjli000616@scu.edu.cn 由于碳质材料具有耐高温、耐辐射、化学稳定性高等很多实用的特性，作为基质的固相萃取剂发展迅速[1]。通常要将对目标元素有特定络合作用的基团引入基质，以改善固相吸附剂对金属离子的选择性[]。本研究选择了富含表面含氧基团的水热炭(HTC)作为固相萃取剂的载体通过接枝红紫酸铵(Mu)，首次得到了对铀酰离子具有高吸附容量和高选择性的新型水热炭质固相萃取剂。 ICP-AES结果显示在大量竞争离子共存条件下(10种离子浓度均为1.0 mmol?L?1)，HTC-Mu对所有离子的总吸附容量为0.503 mmol?g?1，其中对铀酰离子的吸附容量为0.342 mmol?g?1，占总吸附容量的68.0%这充分表明HTC-Mu对铀（VI）具有很好的选择性。HTC-Mu与金属离子的亲和顺序为：UO22+Cr3+ Eu3+ Ni3+ La3+ Ce3+ Co2+Mn2+≈Zn2+≈Sr2+。 在本研究基础之上可能发展合成方法更简单、原料更便宜、对铀吸附性能更好且更加实用的水热炭基固相萃取剂。 关键词：水热炭；红紫酸铵；铀；固相萃取 参考文献 [1] A. Mellah, S. Chegrouche, M. Barkat J. Colloid. Inter. Sci. 2006, 296: 434. [2] S. Sadeghi, E. Sheikhzadeh. J. Hazard. Mater. 2009, 163: 861. Synthesis of Uranium-selective Solid Phase Extractant Using Hydrothermal Carbon as Matrix Qiang Song, Lijian Ma, Jun Liu, Chiyao Bai, Junxia Geng, Hang Wang, Shoujian Li* College of Chemistry, Sichuan University, Chengdu, 610064 * Email: sjli000616@scu.edu.cn Carbon materials were chosen as solid phase matrix because of their chemical stability and radiation and thermal resistance. A new solid phase extractant for selective separation of uranium (VI) was prepared using hydrothermal carbon (HTC) as matrix and murexide (Mu) as ligand. According to the result of competitive adsorption test, the affinity of HTC-Mu toward ions exhibited the following sequence: UO22+Cr3+Eu3+Ni3+La3+Ce3+Co2+Mn2+≈Zn2+≈Sr2+. The total adsorption capacity of HTC-Mu reached 0.50 mmol?g?1 for all ions, and 68% of which was contributed by uranium (VI). The adsorption capacity of uranium (VI) reached 0.34 mmol?g?1. The new solid phase extractant is a promising candidate for the separation of uranium from nuclear effluents. Further study is being undertaken. Key words：Hydrothermal carbon; Murexide; Uranuim; Solid phase extraction