超细硬质合金用钴粉地研究开发.pdfVIP

I11超细硬质合金用钴粉的研究开发 林晨光，李艳，曹瑞军 （1北京有色金属研究总院粉末冶金及特种材料研究所 北京 100088） 摘要：本文总结了近年来超细晶 WC-Co 硬质合金用钴粉的国内外研究开发状况。大量研究结果表明：粘 WC-Co / 结相原料钴粉在制备超细晶 硬质合金中的作用至关重要：采用超细 纳米级粒度的类球形钴粉不仅 可以减少球磨混合时间，同时可降低致密化烧结温度，减少合金中的钴池等缺陷，有助于获得高性能的超 细晶 WC-Co 硬质合金。因此，超细晶 WC-Co 硬质合金的生产在要求粘结相原料钴粉杂质及氧含量低的同 时，对其粒度、粒度分布、颗粒形貌等提出了新的要求。在参考国内外相关工作的基础上，本文作者以 CoCl2 和(NH ) CO 溶液为原料，采用液相沉淀-氢还原法实验室制备了 BET 粒度小于 100nm、氧含量低于 0.8wt% 4 2 3 的钴粉；颗粒形貌呈类球形，粒度分布窄，单分散性好。该工艺技术流程可控、生产成本较低、综合收得 率高、是制备超细和纳米钴粉的有效途径。 关键字：硬质合金；超细；钴粉；液相沉淀-氢还原法 Research and Development of cobalt nanoparticles for ultrafine WC-Co Hardmetals manufacture LIN Chenguang, LI Yan, CAO Ruijun (Powder Metallurgy Special Materials Department, General Research Institute for Non-ferrous Metals, Beijing 100088, China) Abstract: Research and developments status of cobalt nanoparticles for ultrafine and nanocrystalline WC-Co hardmetals were summarized. It is known that Nano-size spherical cobalt powders not only contribute to lower the densification temperature during sintering, but also contribute to shorten the mixing time and diminish cobalt-pool etc. defects. The roles of cobalt nanoparticles are crucial to obtain ultrafine or nanocrystalline WC-Co hardmetals with high performance. The experimental results of nanometer cobalt powder fabricated by liquid phase deposition-hydrogen reduction in Co(II)-(NH ) CO -H O System were introduced. The method 4 2 3 2 was conformed to be an promising synthesis process of spherical cobalt nanoparticles. Keywords: Hardmetals, ultrafine, cobalt powder, precipitation-hydrogen reduction 基金项目：中国博士后科学基金资助项目（20080440334 ）