蛭石吸附地下水中氨氮的实验的研究.pdfVIP

第十二届全国青年材料科学技术研讨会（2009年11 月27-30） 6 绿色建筑与生态环境材料 蛭石吸附地下水中氨氮的实验研究 王明珊，张秀丽，廖立兵 ( 中国地质大学材料科学与工程学院，北京，中国，100083) 摘 要：蛭石作为一种天然矿物材料因其具有吸附、阳离子交换等性质被广泛应用于废水处理领域。国内 外均有学者对蛭石吸附工业废水中高浓度氨氮的效果进行过研究，然而对于蛭石吸附低浓度氨氮的研究尚 未见报道。本文进行了蛭石吸附地下水中低浓度氨氮的试验。研究了蛭石粒径、用量、环境pH 值、温度、 时间对蛭石吸附氨氮的影响。通过对吸附前后的蛭石进行 XRD 、TG-DTA 、IR 分析和对吸附前后溶液中 2+ Mg 等金属阳离子浓度进行分析，讨论了蛭石吸附去除氨氮的机理。实验结果表明，在氨氮浓度为10mg/L 的条件下，蛭石吸附氨氮的平衡时间为5h ，最佳pH 值约6-7 ， 60 ℃最利于蛭石对氨氮的吸附，与高氨氮 浓度条件下不同。蛭石粒径越小，吸附氨氮的能力越强。蛭石吸附氨氮后，层间距略微增大，吸附前后热 失重增加，红外光谱中水的O-H 振动向低频率移动，吸附后的溶液中Mg2+ 等金属离子浓度增大。表明蛭石 主要通过层间离子交换吸附去除氨氮，氨氮进入层间后交换出层间的阳离子，导致O-H 振动和失重量发生 变化。 关键词：蛭石；氨氮；吸附 Adsorption of Low Concentration Ammonium onto Vermiculite WANG Mingshan,ZHANG xiuli,LIAO libing (School of Material Sciences and Technology, China University of Geosciences, Beijing , 100083) Abstract ：Vermiculite is a kind of layered silicate with good adsorption and ion exchange properties. Its adsorption for high concentrations ammonium has been studied. This paper studied the adsorption behavior of low concentrations ammonium on vermiculite in solutions. The effects of vermiculite particle size, the dosage of vermiculite, pH, temperature, adsorption time on the adsorption of ammonium on vermiculite were investigated. Vermiculites were characterized by X-ray diffraction, TG-DTA and IR analysis. The change of cation concentration after adsorption was measured. Results shown that the optimum adsorption conditions of low concentration ammonium (10mg/L) on vermiculite are: balanced adsorption time= 5 hours, pH= 6-7, temperature=60 ℃, which is different from that for high concentration ammonium adsorption. The smaller the particle size of vermiculit