颗粒活性炭吸附二甲基三硫与β-环柠檬醛的性能与机理研究.pdfVIP

颗粒活性炭吸附二甲基三硫和13I．环柠檬醛的性能 和机理研究 成银高乃云戎文磊周圣东 (1．同济大学污染控制与资源化研究国家重点实验室，上海200092；2．无锡市自来水总公司，无锡214031) 摘要：以饮用水源中两种典型的嗅味物质二甲基三硫(dimethyllfisulfide)和p．环柠檬醛 (肛cyclocitral)为研究对象，分别从吸附平衡试验和吸附动力学方面研究了颗粒活性炭 (GAC)吸附二甲基三硫和B．环柠檬醛，此外，考察了溶液pH对吸附效果的影响．结果表 明，GAC吸附二甲基三硫和B．环柠檬醛均同时符合伪一级反应动力学和伪二级反应动力学 模型；在4种等温吸附模型中，Freundlich方程能最好拟合吸附等温线；GAC对二甲基三硫 和}环柠檬醛的吸附容量较大，当二甲基三硫和B一环柠檬醛的初始浓度为500烬／L时，吸 附容量分别达到8．680和16．041 L／mg；pH10的条件更有利于GAC吸附二甲基三硫，而 pH(2．13)对B．环柠檬醛的吸附效果无显著影响． 关键词：二甲基三硫；p．环柠檬醛；颗粒活性炭；嗅味物质；吸附 on andmechanismof Trisulfide Studyperformance Dimethyl and adsorbedGranularactivatedcarbon 13-cyclocitralby (State ofPofiufionControland rayLaboratory ResOUI∞Reuse，Ton商iUniversity,ShanghaiCi桫200092， China) and odorantsin trisulfide weretwo Abstract：dimethyl typical pcyclocitral water,particularly relatedto and activated of cyanobacteria．Granular algae carbon(GAC)adsorptiondimethyl was trisulfideor studiedfromthe ofkineticsand the 13-cyclocitral standpoint equilibria．Also influenceof tothe was resultsshowthattheGAC of pH adsorptioninvestigated．111e adsorption trisulfideor wasconsistentwitll first-orderand second-order dimethyl I，-cycloeitral pseudo pseudo kinetics thefour isotherm isothermshowedthe models，Freundlich models．Amongtwo-parameter best wi也the datainGAC ofeitherof trisulfideor fitting equilibrium adsorption dim