三草酸合铁(Ⅲ)酸钾制备实验的改进探索.pdfVIP

第 35 卷第 2 期 2013 年 3 月 Vol.35 No.2 Journal of Tangshan Teachers College Mar. 2013 三草酸合铁(III)酸钾制备实验的改进探索 刘冬莲，刘娅萍，刘 爽，张 宁 （唐山师范学院化学系，河北 唐山 063000 ） 摘 要：根据三草酸合铁(III)酸钾K [Fe(C O ) ]·3H O 制备实验的实际情况，对反应温度、H O 去除时间、 3 2 4 3 2 2 2 Fe(OH) 溶解温度、KHC O 加入方式进行了探究。通过优化实验过程，可得到粒度较大的翠绿色晶体，提高了 3 2 4 产率和实验教学效果。 关键词：三草酸合铁(III)酸钾；制备；实验改进 G642.0 A 1009-9115(2013)02-0017-03 中图分类号： 文献标识码： 文章编号： DOI ：10.3969/j.issn.1009-9115.2013.02.006 Conditions Optimization for the Preparation of Potassium Ferrioxalate LIU Donglian, LIU Yaping, LIU Shang, ZHANG Ning (Department of Chemistry, Tangshan Teachers College, Tangshan 063000, China) Abstract: The experimental conditions were optimized for the preparation of potassium ferrioxalate according to the practice of experiments, and the temperature, the remove time of H O the solubolity temperature of Fe(OH) and the addition of oxalic were 2 2, 3 explored in the preparation of potassium ferrioxalate. By optimizing experimental process, we can obtain the emerald crystal grains in improved process, and the yield was increased. The effectiveness of experimental teaching was ameliorated. Key Words: potassium ferrioxalate; preparation; experimental innovation 几年来，我们通过无机化学精品课程的建设，对实验 颗粒晶体，只得到较少的产物或仅得到较少量且含有杂质 课内容和体系进行了深入的改革和探索，在整合优化实验 较多的黄绿色粉末，有的甚至无法得到晶体，这既会削弱 项目的基础上，增加了综合性、设计性实验的比例，取得