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PREPARATION OF CARBON NANOFIBERS BY POLYMER BLEND TECHNIQUE.pdf
维普资讯
ChineseJournalofReactivePolymers
2007,16(1-2):108~111
Article:1004-·7646(2007)02--0108--04
PREPAR rIoN oFCARBONNANOFIBERS
BYPOLYMERBLENDTECHNIQUE
LING Fen YANG Pengfei Wei YANG Shenglin LIGuang
CollegeofMaterialScienceandEngineering,DonghuaUniversity,Shanghai200051,China.
Abstract:Thepolymerblendtechniqueisanovelme~odtoproducedcarbonnanofibers.Inthis
paper,wehavepreparedfinecarbonfibersandporouscarbonmaterialsbythistechnique,andwe
willdiscusstheexperimentresultsbymeansofSEM,TGA,ElementAnalysis,etc.
Keyword:Carbonnanofibers;Po~merblend;Wet—spinning;Compatibility;Morphology.
LibraryClassificationNo.:TQ342 LiteratureMark:A
1.INTRoDUCTIoN
CarbonfiberiSonekindofhighperformancefiberswhichshowsveryimportantusesinmnay
fields .CarbonnanofiberlSanew form ofcarbonfiberwithnanometersizeindiameternad
greatratiooflengthoverdima eter.Thereportedmethodtopreparenanocrabonfiberincludes
vaporgrowth,staticspinning Recentlypolymerblendtechniquehasbeen developedasa
novelmethod to preprae crabon nano materials,including crabon nanotubes and crabon
nanofibersta-oJInthispaper,anew methodtopreparecrabonnanofibersbythepolymerblend
.
techniquewaspresented.Th emorphologyofcrabonnanofiberswasinvestigated.
2.EXPERIM ENT
Polymethylmehtacrylate(PMMA),polyvinylchloride(PVC),polystyrene(PS)wereusedas
thethemr allydecomposablepolymer(TDP);andPolyacrylonitrile(PAN)ascrabonprecursor
polymer(CPP).CPPandTDPpolymerblendswergprepraedthroughsolutionmixing.The
blendfiberswereobtainedafterwetspinning.Theoxidizationandcarbonizationwasmadeto
removeTDP。Th ecarbonnanofiberswereprepraedinthisWay.nI theoxidizationprocess.the
fibersareheatedintheairinna environmentwhosetemperatureincreasesfrom 180℃ t
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