“糖葫芦状”铜短碳纤维复合增强体的制备和机理研究.pdfVIP

第十二届全国青年材料科学技术研讨会（2009年11 月27-30） 8 复合材料 “糖葫芦状”铜短碳纤维复合增强体的 制备及机理研究 李微微，刘磊，胡文彬 （上海交通大学材料科学与工程学院，上海 200240 ） 摘 要：本文采用电化学沉积的方法制备了“糖葫芦状”铜短碳纤维复合增强体，并采用SEM、XPS 、DSC等分 析测试技术对其沉积机理进行研究。实验中首先将短碳纤维在450 oC下煅烧1h，然后将其均匀分散在镀液中 （50g/L CuSO ·5H O+10g/L 酒石酸钠+90g/L 柠檬酸钠+12g/L KNO ），调节不同电压，得到“糖葫芦状”铜短碳 4 2 3 纤维复合增强体。经过分析，得出的结论是，煅烧处理后的碳纤维表面活性含氧基团-OH和C=O含量升高，这 些活性点使得纤维表面的电位降低。对于电镀铜来说，外加沉积电位以及活性基团自身更低电极电位的加成作 用才是氧化还原反应的驱动力，当外加电位较低时，只有具有活性基团的位置才能发生反应沉积出铜，其他位 置由于不能满足反应所需的最小驱动力而不能反应，因此形成“糖葫芦”结构。 关键词: 复合材料；糖葫芦结构；电沉积；机理 Preparation and mechanism of “spiky ball” structural Cu-deposited short carbon fiber by electrodeposition LI Weiwei, LEI Lei, HU Wenbin (School of Materials Science and Engineering, Shanghai Jiaotong University, Shanghai 200240) Abstract ：“Spiky ball” structural Cu-deposited short carbon fiber was prepared by electrodeposition and characterized by SEM 、XPS and DSC. SCFs were heat treated at 450°C in air for 60min. A sulfuric acid bath (50g/L CuSO ·5H O) 4 2 was used as the basic plating bath. A homogeneous dispersion of SCFs was achieved with ultrasonic agitation. The composition of the composite plating bath was 50g/L CuSO ·5H O+10g/L sodium tartrate+90g/L sodium citrate+12 g/L 4 2 KNO3. Plating was performed at room temperature with magnetic stirrer. “Spiky ball” structural Cu-deposited short carbon fiber could be obtained by adjusting different voltages. The contents of –OH and C=O were increased by calcining carbon fib