废旧尼龙6在亚超临界水中解聚产物的分析研究.pdfVIP

废旧尼龙6 在亚超临界水中解聚产物的分析研究 詹世平 何友宝 王晓宁 丁仕强 (大连大学环境与化学工程学院，大连116622) 摘 要 在以往研究基础之上，进一步确定了废旧尼龙 6 在亚超临界水中解聚的主要产物种类，考察 了不同的反应温度、反应压力、反应时间对液相产物收率的影响，并提出了解聚进程。实验结果表明：液 相产物为氨基己酸和己内酰胺，最大收率分别为 6.6%和 96% ；解聚反应为连续反应，尼龙6 先被水解为 氨基己酸，后经环化脱水为己内酰胺或进一步分解为低分子物质。研究得出了每一种反应进程下的速率常 数k 和表观活化能Ea 的值。 关键词 废旧尼龙6 亚超临界水 解聚 产物 中图分类号 X703.1 文献标识码 A 文章编号 Study on the analysis of depolymerization products of waste nylon6 in subcritical and supercritical water Zhan Shiping He Youbao Wang Xiaoning Ding Shiqiang ( College of Environmental and Chemical Engineering, Dalian University, Dalian 116622) Abstract Based on previous work, the sort of main depolymerization product of waste nylon6 in sub critical and supercritical water was further determined. The influences of temperature, pressure, and reaction time on the yield of the liquid phase products were studied. The depolymerization mechanism was proposed. The results showed that the main products in liquid were aminocaproic acid and caprolactam, the maximum yield was 6.6% and 96%, respectively. The reaction scheme of nylon 6 decomposition is represented. Nylon 6 was decomposed into aminocaproic acid by hydrolysis followed by cyclodehydration to caprolactam or decomposition further to lower molecules. At each reaction conditions, the k values were determined and the activation energy Ea was calculated. Key words waste nylon6; subcritical and supercritical water; depolymerization; products [1] 聚酰胺6，俗称尼龙6。它是由氨基己酸或己内酰胺聚合而得的产物 。以往的研究，重点多集中于解 聚工艺的设计，解聚条件的确定及液相主产物己内酰胺的定量[2-9]。如2000 年Shibata 和Masuda [10]采用不 锈钢间歇炉型反应釜，进行了以超临界水为溶剂，快速解聚尼龙6 和回收己内酰胺的实验研究。得出己内 酰胺最佳反应条件为：380℃，20MPa 下反应10min 时，收率为86%。2004 年刘爱学等[11]研究了尼龙6