可聚合二苯甲酮衍生物光引发剂的合成和其光聚合性质.pdfVIP

可聚合二苯甲酮衍生物光引发剂的合成及其光聚合性质(5) 朱晓丹1伍文涛1 方大为2聂俊2* 马贵平2 1.常州大学，江苏常州 2131642.北京化工大学，北京 100029 针对传统二苯甲酮熔点低、分子量小、易挥发，在固化膜中易向表面迁移析出，产生毒性 等缺点[1,2]，本文通过4-（2，3-环氧丙氧基）二苯甲酮(EBP)与丙烯酸在阻聚剂存在的条件 下合成了含有不饱和双键的可聚合光引发剂4-(丙烯酸-2-羟基丙酯-3-氧基)二苯甲酮 （AEBP），采用红外光谱、紫外光谱及核磁氢谱对其结构进行表征，利用实时红外光谱研 究其光聚合性质。 Synthesisandphotopolymerizationpropertiesofcurable benzophenonederivativephotoinitiator WUWentao1FANGDawei2NIEJun2 ZHUXiaodan1 MAGuiping2* 1.ChangzhouUniversity,Changzhou,Jiangsu213164 2.BeijingUniversityofChemicalTechnology,Beijing100029 Abstract:Benzophenoneisacommonhydrogenabstraction(TypeⅡ)photoinitiator,itowns advantagesofsimplestructure,easytosynthesizeandhighinitiatedactivities,however,the disadvantagesofeasytomigratetothesurface,producingtoxicandlowmolecularweightrestrict itsapplicationsinfoodstuffanddrugpackaging.Inordertosolvethisproblemeffectively, curablebenzophenone derivativephotoinitiator4-(acrylic acid-2-propylparaben-3-epoxide) benzophenone(AEBP)hasbeensynthesizedby4-(2,3-epoxypropyloxy)benzophenone(EBP)and acylicacidinthispaper,thestructureofthisnewphotoinitiatorischaracterizedbyFT-IR,UV-vis absorptionspectra,and1HNMR,thephotopolymerizationpropertiesarestudiedbyReal-Time Infrared(RT-IR)spectra.TheresultsshowthatthegreaterAEBPconcentration,thefaster polymerizationrateandthehigherdoublebondconversion,theinitiationefficiencyofAEBPis similartothatofBP. Keywords:Photopolymerization ; Curablebenzophenone ; RT-IR