聚乙烯―碳黑复合材料的太赫兹时域光谱测量研究.pdfVIP

理化学学报(Wuli Huaxue Xuebao) February A cta Phys. Chim. Sin., 2007, 23(2) ：177-180 177 [Article] 聚乙烯碳黑复合材料的太赫兹时域光谱研究 玉峰1, 2 朱智勇1, 吉 特1 葛 敏1 陈西良1 刘 崎1 (1 中国科学院上海应用物理研究所, 上海 201800; 2 中国科学院研究生院, 北京 100049) 摘要： 利用太赫兹时域光谱(THz TDS)技术在0.3-2.0 THz 频率区间测量了不同碳黑含量( )的聚乙烯碳黑复 合材料光电性质随频率的变化及其与碳黑含量之间的关系. 测量发现, 随碳黑含量的增加, 复合体系的吸收系数 逐渐增大, 并伴随折射率的相应增加. 在碳黑含量确定的情况下, 材料的吸收系数随频率的增加而增大, 但折射 率随频率的增加而略有减小. 在假定复合体系中孤立碳黑颗粒在外电场 用下的极化过程是引起材料太赫兹频 区介电损耗主要因素的情况下, 利用德拜偶极子弛豫理论对聚乙烯碳黑复合材料的介电行为进行了解释. ； ； 关键词： 聚乙烯碳黑复合材料 太赫兹时域光谱 介电性质 中图分类号： O649, O657.99 THz Time domain Spectroscopic Study of Polyethylene Carbon Black Composites SONG Yu Feng1, 2 ZHU Zhi Yong1, JI Te1 GE Min1 CHEN Xi Liang1 LIU Qi1 1 ( Shanghai Institute of App lied Physics, Chines Academy of Sciences, Shanghai 201800, P. R. China; 2Graduate School of the Chinese A cademy of Sciences, Beijing 100049, P. R. China) Abstract ： Terahertz time domain spectroscopic technique was applied to investigate the optical properties of polyethylene carbon black composites in the frequency range of 0.3-2.0 THz as a function of frequency and volume fraction of the carbon black. It is found that the absorption coefficient and the refractive index of the composite increased with increase of carbon black content. At the same carbon black concentration, the absorption coefficient increased and the refractive index decreased with increase of frequency. The experimental measurements were analyzed by using