CeO2纳米晶包覆介孔碳%2f硫的电化学性能的研究.pdfVIP

CeO 纳米晶包覆介孔碳/硫的电化学性能研究 2 马国强，温兆银，王清松，靳俊，吴相伟，张敬超 （中国科学院 上海硅酸盐研究所，中国科学院能量转换材料重点实验室；上海无机能源材料与电源工程 技术研究中心，上海200050) 摘要 为提高锂硫电池的性能，具有三维孔道结构的介孔碳CMK-8 被用作硫的载体。并以 Ce(OH) 为原料，采用热分解法制备得到粒径小于10nm 的CeO 纳米晶。而后将CeO 纳米 4 2 2 晶均匀分散在介孔碳CMK-8/S 复合物表面，进一步防止活性物质的团聚和吸附多硫化锂。 研究表明，该电极材料显示出优越的电化学性能。电池阻抗降低，且前几周容量的快速衰减 -1 得到抑制。其中，在0.5C 倍率下，电池循环100 周之后，电池放电比容量维持在810mAh.g ， 其库伦效率达95% 以上，远高于没有CeO2 纳米晶添加的电极材料。 关键词：锂硫电池；介孔碳； CeO2 纳米晶；电极添加剂；循环性能 The electrochemical properties of CeO2 nano-crystal wrapped mesoporous carbon/S cathode for Lithium/sulfur batteries Guoqiang Ma, Zhaoyin Wen*, Qingsong Wang, Jun Jin,Yanming Cui, Xiangwei Wu, Jingchao Zhang CAS Key Laboratory of Materials for Energy Conversion, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, P.R. China Abstract: 3D structural mesoporous carbon CMK-8 was used as the matrix of sulfur to enhance the performance of Li-S battery. Furthermore, CeO2 nano-crystal less than 10nm was fabricated by using thermal decomposition method with Ce(OH)4 as the raw material. Then CeO2 nano-crystal was dispersed on the surface of CMK-8/S composite to further improve the adsorption effect between cathode and lithium polysulfides and inhibit the aggregation of sulfur. The results show that an enhanced electrochemical performance was obtained including the decreased AC impedance value, the enhanced cycle performance and the improved coulombic efficiency. The specific capacity retained at around 810mAh.g-1 at 0.5C even after 100cycles, and the coulombic efficiency is more than