Sn含量对Zr-Sn-Nb-Fe-Cr合金相变温度与沉淀析出相的影响.pdfVIP

第十二届全国青年材料科学技术研讨会（2009年11 月27-30） 3 有色金属材料 Sn 含量对 Zr-Sn-Nb-Fe-Cr 合金相变温度和 沉淀析出相的影响 1 1 1 2 2 2 1 过锡川 ，栾佰峰 ，陈建伟 ，周军 ，张喜燕 ，李中奎 ，刘庆 (1. 重庆大学材料科学与工程学院，重庆 400044) （2. 西北有色金属研究院，西安 710016 ） 摘 要：本文以Zr-1.0Sn-0.3Nb-0.3Fe-0.1Cr 与Zr-0.8Sn-0.3Nb-0.3Fe-0.1Cr 两种不同Sn 含量锆合金为研究对 象，采用差示扫描量热法（DSC ）测量了两种锆合金的相变温度，探讨了Sn 元素含量变化对锆合金相变点 的影响。同时采用扫描电子显微镜（SEM ）对热轧态、热轧退火态、冷轧态、冷轧退火态、终轧态、终轧 退火态六种加工工序样品分别进行了详细的微观组织观察，随后通过定量金相法对两种锆合金在不同加工 工序下第二相大小及分布等特点进行了对比分析研究，得出两种锆合金定量的统计结果。降低Sn 含量后 α→β相变点降低3℃左右，而沉淀析出相颗粒形状结构基本不变，但是第二相颗粒平均尺寸减小。扫描电 镜中能谱（EDS ）分析半定量地说明了Sn 在锆合金中存在不同程度的成分偏析。 关键词：锆合金；相变温度；定量金相；能谱 （EDS ）；沉淀析出 Effect of Sn content on the phase transformation temperature and precipitation of Zr-Sn-Nb-Fe-Cr Zirconium alloy GUO Xichuan, LUAN Baifeng, Qiu Risheng, ZHANG Xiyan, LIU Qing (Department of Material Science and Engineering, Chongqing, 400044) Abstract: In this paper, precipitation and phase transformation temperature of both zirconium alloys, which were Zr-1Sn-0.3Nb-0.3Fe-0.1Cr alloy and Zr-0.8Sn-0.3Nb-0.3Fe-0.1Cr alloy respectively, were investigated and the results were illustrated. Those zirconium samples were obtained from different processing, including hot rolled, annealed, cold rolling, annealed, final rolled, final annealed. First, the temperatures of phase transformation of both alloys were experimented by means of Differential Scanning Calorimetric (DSC) and the effect of Sn on the phase transformation temperature was also discussed. Second, the quantitative results, including the size and volume fraction of precipitates of both alloys were also calculated through quantitative metallographic. The temperature of α→β phase transformation decreased about 3 ℃with the decreasing