异氰酸酯改性与应用_阎宏永.pdfVIP

37 8 V o.l 37 N o. 8 2007 8 PA INT COAT INGS INDU STRY Aug. 2007 阎宏永, 刘翠云, 付青存, 宋文生, 李国芝, 张玉清 河南科技大学高分子科学与纳米技术 点实验室, 河南洛阳 47100 3 : , , : ; ; ; ; : TQ 6304 : A : 0253- 43 12 2007 0 8- 0063- 04 M odification and Application of Isocyanates Y an H ongyong, Fu Q ngcun, Song W ensheng, L Guozh , Zhang Y uq ng K ey L a bor tary of P olymer Sc ience and N ano- technology, H enan Un iversity of Sc ience and Tech no logy, Luoyang, H enan, 47 100 3, Ch ina Abstract: The var et es of socyanates are lm ted. T he m od f cat on of socyanates m ay ex tend the spe- c es o f socyanates, mprove the r appl cat on perform ance, and enhance the propert es o f po lyurethane m ate- r als. M ethods for the m od f cat on of socyanates nclude process o f urethane, d m er zat on, trm er zat on, b uret, carbod m de, and block ng react on, etc. K ey Words: socyanate; m od f cat on; tr m er zat on; b uret; block ng 0 : , ; , ; , , ; , [ 3] , , [ 1] , , , , TD I M D I , IPD I PAP I , HD I , , , NCO , , , , , ; , , ; 1 , , ; , , , , [ 2] , , , , [ 基金项目] 河南科技大学博士启动基金, 河南科技大学科研基金资助项目 2004ZY 043 , 河南省高等学校青年骨干教师资助计划项目 豫教高 [ 2005 ] 46 1 号 作者简介: 阎宏永 1979 , 男, 硕士研究生, 师从宋文生老师, 从事聚氨酯原材料及应用基础研究 63 , : M D I NCO , TD I, , M D I TM P , TD IIPD I M D I , M D I TM P TD I- TM PIPD I- TM P , [ 13] TD I- TM P , 5 TD I- TM P , TD I , , , , TD I 4 N CO 2 N CO, 4 NCO TM P , , 4 NCO 100% , [ 4] , , , , , , , ; 2 , ; TD I TM P , TD I TM P 31, , [ 14] , TD I , , TD ITD I, , , TD I 175 , [ 5- 6] [ 7] TD I, , TD I; [ 8- 9] [ 10] , 80 , , Bayer D esmodur L , TD I TD I- TM P , , TD I , 07% TD I- TM P , , , , , , TD I, , , , IPD I - TM P TD I - , NCO, NCO TM P IPD I- TM P TD I- TM P IPD I 3 , , , IPD I IPD I- Hls IP- , D I- TM P IPD I 3% , IPD I , IPD IIPD I - TM P, , , [ 11] , , , 2 , , [ 12] , , , , , , , , ; , [ 15] , TD I, CH , 3 , , ; 4, 4 - , , 64 , : ; , NN N - 1- - 3 - N - - 1- , ; , , , [ 17- 18] , , M D