CuOα-Fe2O3纳米催化剂的制备及其催化性能.pdfVIP

石油学报(石油加工) ACTA PROCESSINGSECTION) 2008年10月 PETROI。ElSINICA(PETROI．EUM 增刊 文章编号：1001—8719(2008)增刊一0306—04 CuO／a—Fe203纳米催化剂的制备及其催化性能 曹建亮1，袁忠勇1，朱伟东2 (1．南开大学化学学院新催化材料科学研究所，天津300071；2．浙江师范大学物理化学研究所，浙zr金华321004) 摘要：采用沉积一沉降法将CuO负载在商品级a-Fe：0。粉末载体上，制备出CuO／a-Fe：0。纳米催化剂。采用 XRD、TEM、H：一TPR等手段对其结构性能进行表征，并在连续流动微反装置上考察了其对CO低温氧化的催 温氧化催化活性。 关键词：旷氧化铁；氧化铜；负载型催化剂；低温CO氧化 中图分类号：0643 文献标识码：A PREPARATIONANDCATALYTICACTIVITYOF CuO／a-Fez03 CAO Jian—lian91，YUANZhong—yon91，ZHUWei—don92 (1．InstituteNew Materials of Catalytic Science，Collegeof 300071，China； Chemistry，NanhaiUniveristy，Tianjin 2．Institute Normal 321004，China) ofPhysicalChemistry·ZhejiangUniversity，Jinhua usedas ofCuO Abstract：Commerciala-Fe203 were support Cu0／口_Fe203nanocatalysts powders nanoparticles．The wereobtaineda werecharacterizedXRD，TEMand by deposition-precipitation(DP)method，whichby H2一TPR in were inamicroreactor-GC COoxidationexamined techniques．Theircatalyticpropertieslow-temperature system． TEMand resultsshowedthatCuO were onthesurfaceof Hz—TPRanalysis nanoparticleshighlydispersed between be commerciala-Fe203 a interactionthemcouldfound．TheseCuO／ powdersupport，andstrongsynergistic wereactivefor COoxidation，andtheonewithlO％CuO showed a-Fe203nanocatalysts