FCC汽油选择性HDS催化剂Co-Mo镁铝尖晶石-Al2O3的研制.pdfVIP

石油学报(石油加工) 2010年8月 ACTAPETROLEISINICA(PETROl。EUMPROCESSINGSECTION) 第26卷第4期 文章编号：1001—8719(2010)04—0499—07 尖晶石一A1203的研制 孔会清，张孔远，张景成，柴永明，刘晨光 (中国石油大学重质油国家重点实验室，CNPC催化重点实验室，山东青岛266555) 载体的酸性，减弱了金属与载体的相互作用，提高了催化活性，降低了反应温度，从而使催化剂的HDS选择性因 选择性因子达到最大值。 关键词：镁铝尖晶石(MgAI：O。)；载体改性；FCC汽油；加氢脱硫(HDS)；选择性因子 中图分类号：TE624．9；TE624．4；TQ426．82文献标识码：A PREPARATIoNSELECTIVEHYDRoDESULFURIZATIoNCATALYST 04一A12ojFORFCCGASOLINE Co—Mo／MgAl2 KONG Huiqing，ZHANGKongyuan，ZHANGJingcheng，CHAIYongming，LIUChenguang Oil (StateKeyLaboratoryofHeavyProcessing。KeyLaboratoryofCatalysis，CNPC， China 266555，China) UniversityofPetroleum，Qfngdao wasmodified aseriesofmodified Abstract：The弘A1203 bymagnesium-aluminum04)，and spinel(MgAl2 Co-Mo method．The 产烈203 catalysts(Co-Mo／MgAl204一～203)werepreparedby supported impregnation of wereevaluatedinfl hydrodesulfurization(HDS)performancesCo—Mo／MgAl204-A1203 micro—reactor asfeedstock，andtheHDS high-pressure system，byusingcatalyticcrackinggasoline modified factorwascalculated．The and werecharacterizedmethods selectivity supportscatalysts by of and that TPR．Theresultsindicated N2adsorption-desorption，XRD，NH3-TPD，Py—IR 04一A12showedHDS and