尿素合成塔衬里外壁开裂原因分析.pdf

Hot 2013，V01．42，No．18 WorkingTechnology 尿素合成塔衬里外壁开裂原因分析 徐晓丹l，谢毅-，张洪建乙葛建平3李海4 (1．江苏特检院，江苏南京210003；2．江苏特检院扬州分院，江苏扬州225003；3．江苏特检院徐州分院，江苏徐 州221000：4．常州大学，江苏常州213164) 摘要：采用光学显微金相、X射线衍射、扫描电镜及能谱等方法，分析了某厂尿素塔衬里外壁开裂原因。实验表 明，由于衬里外壁在氨气检漏过程中形成特定腐蚀环境，使得316L钢固溶处理后残留的粗大Fc-CroNi-Mo相和铁素体 相发生点蚀形成应力集中源。焊接过程中造成热影响区局部or相析出、脆化以及残余拉应力状态，三者共同作用下导 致尿素合成塔外壁在长期服役过程中发生应力腐蚀开裂。 关键词：尿素塔；衬里；应力腐蚀开裂；析出脆化 中图分类号：TGl57 文献标识码：A 文章编号：1001-3814(2013)18-0200—03 on ReasonforLinerMaterialofSomeUrea Tower AnalysisCracking Synthetic XU Hai4 Xiaodanl，XⅢYil，ZHANGHongjian2，GEJianpin93，LI Instituteof SupervisionInspection JiangsuProvince，Nanjing210003，China；2．Jiangsu (1．SpecialEquipmentSafety Province Institute Safety InspectionYangzhouBranch，Yangzhou225003，China；3．Jiangsu SpecialEquipmentSupervision Province InstituteXuzhou 22 SpecialEquipmentSafetySupervisionInspection Branch，Xuzhou1000，China；4．Changzhou University，Changzhou213164，China) reasonsforthelinermaterialofsomeurea towerwere Abstract：The analyzedoptical cracking synthetic using forms veneer andEDS．Theresultsshowthatthecorrosiveenvironmentbetweenlinermaterialand microscopy,XRD．SEM sheet theammonialeakdetection andresulminthe ofFe--Cr-Ni··Moandferrite which during process pitting phase phase in remainedthe316Lstainlesssteelaftersolutiontreatment．‰combinedeffect emb