20131019关俊卿(作者修回稿)高温共烧铂电极浆料的制备研究.doc

高温共烧铂电极浆料的制备研究 (北京有色金属研究总院 有研亿金新材料股份有限公司 102200) 摘 要：汽车所用的片式氧传感器需要多层高温共烧结制备，烧结温度大于1500℃，如此高的烧结温度对铂电极浆料的耐热性提出较高的要求，要求反应铂电极浆料有较高耐热性能，高温烧结收缩较小，反应电极有高致密性多孔层叠的结构进而使得铂电极-YSZ-气体三相界面增长，使得片式氧传感器的氧敏响应性能和催化性能显著提高；要求加热铂电极要有致密的结构，阻值稳定，连续性好，长时间通电不易烧断。传统的铂电极浆料烧结温度为8001200℃，明显不能满足高温烧结的需要。本文制备了适用于高温烧结的铂反应电极浆料和铂加热电极浆料。 关键词：高温共烧；铂电极浆料；片式氧传感器 中图分类号： 文献标识码： 文章编号：1004-0676(201)S1-0000-00 Preparation of High Temperature Co-sintering Platinum Electrode pastes GUAN Junqing, HE Xin, CHEN Qiao, XIONG Xiaodong, CHEN Fei, WU Song (GRIKIN Advanced Materials Co. Ltd., General Research Institute for Nonferrous Metals, Beijing 102200, China) Abstract: Chip oxygen sensor for automobiles needs multi-layer high temperature co-sintering processing, the sintering temperature is higher than 1500℃, the high sintering temperature requires higher heat resistance and small shrinkage during sintering of platinum electrode pastes. Because of the structure of the reactive electrode has high density porous laminated, and then makes the platinum electrode- YSZ- gas phase interface significant growth, makes the planar oxygen sensor’s oxygen sensitive properties and catalytic performance improved significantly. The structure of the heating platinum electrode is dense, stable resistance, good continuity, long time power is not easy to burn. The sintering temperature of traditional platinum electrode pastes is 800~1200℃, it obviously can not meet the need of high temperature sintering. In this paper the reactive platinum electrode paste and heating platinum electrode paste suitable for high temperature sintering were prepared. Key words: metal material; high temperature co-sintering; platinum electrode paste; chip oxygen sensor 汽车氧传感器[1]是电喷汽车三元催化转化必不可少的元件，目前常用的汽车氧传感器为片式氧传感器[2]，与传统的管式氧传感器相比，片式氧传感器的制备需要在高温下(1500℃)共烧成型，因此作为片式氧传感器最主要的两个功能电极，反应铂电极和加热铂电极的高温共烧性能决定着氧传感器性能。 反应铂电极为了获得较高的催化能力，必须具有多孔层叠结构，从而获得较长的O2、Pt/YSZ三相界面[34]。而加热铂电极为了获得高可靠、长寿命的加热能力，要求加热电极阻值均匀一致。因此铂电极高温烧结后的微观结构直接影响着氧传感器的性能和使用寿命，对所用的铂电极浆料提出了苛刻的要求。本文通过改变超