Ca掺杂的GdBaCo2O5+δ的制备和物性研究.pdf

· 58· 材料导报B：研究篇 Ca掺杂的GdBaC0205+6的制备和物性研究’ 张亚梅1，吴小山2，刘家欢1‘ (1江苏科技大学物理系，镇江212003；2南京大学固体微结构物理国家重点实验室，南京210093) 摘要 采用固相反应法制备了Gdl--xCa．BaCoz05+d(z一0、0．1、0．2)层状钙钛矿钴氧化物，通过XRD、SEM、 TG和四线法研究了材料的制备和物理性能。结果表明，Ca掺杂的样品主相具有母相GdBaCo。【)5+a的晶体结构，还 存在杂相BaC002．6；晶胞参数和体积随Ca掺杂量的增加而减小。从室温到1000K，所有样品都经历了金属绝缘体转 变和结构相变，Ca掺杂样品的电导率得到大大提高，约为母相的2倍。 关键词 固相反应法电导率金属绝缘体转变 中图分类号：()472+．4；0649．4文献标识码：A TheFabricationand ResearchofCa GdBaC02 PhysicalProperties Doped 05+6 ZHANG Yameil，WUXiaoshan2，LIUJiahuanl (1 of ofScienceand 212003；2National ofSolidState DeparmentPhysics，JiangsuUniversity Technology，Zhenjiang Laboratory of 210093) Microstructures，DepartmentPhysics，NanjingUniversity。Nanjing Abstract cobaltoxides solid Layeredperovskite Gdl一，CaiBaC0205+8(z一0，0．1，0．2)weresynthesizedby state reaction．Thefabricationand were andfourwiremethod． physicalpropertiesinvestigatedbyⅪ①，SEM，TG The resultsshowthatCa havethemain of(猁＆(hOs+a structureandalso experirnental dopedsamples phase crystal havethe uniteell andvolumeofallthe decreasewithCa impurityphaseBaC002．6；theparmameters samples doping content room tO the 1000K，all metalinsulatortransitionandstruc— increasing．Fromtemperature samplesexperience ture transition．TheofCa are andtwiceas asthatofthe phase conductivitydopedsamplesgreatlyimproved big parent GdBaC02