SBA-15不饱和聚酯树脂的制备及其性能研究.pdf

绝缘材料 2014 ，47(2) 卢凤英等：SBA-15/不饱和聚酯树脂的制备及其性能研究 41 SBA-15/不饱和聚酯树脂的制备及其性能研究 卢凤英，吕 建，胡舒龙，章 震，刘华山，曾德明 （桂林理工大学 材料科学与工程学院，有色金属及材料加工新技术教育部重点实验室， 省部共建广西有色金属及特色材料加工国家重点实验室培育基地，广西 桂林 541004） 摘要：采用原位聚合法制备了介孔材料/不饱和聚酯(SBA-15/UP)复合树脂，通过X 射线衍射（XRD ）、氮气吸 附-脱附、热重分析（TGA ）等表征了SBA-15及SBA-15/UP 的相关性能，研究了不同SBA-15含量对SBA-15/ UP 热性能及电性能的影响。结果表明：在原位聚合过程中，SBA-15 的有序性降低，其孔径由原来的6.64 nm 下降到0.926 nm ，表明UP 分子链嵌入到SBA-15孔道内形成了有机-无机互穿网络结构；与纯UP 相比，添加 1%~3%的SBA-15后，SBA-15/UP 复合树脂的热稳定性明显提高，其Td5%较纯UP 的Td5%均提高了25 ℃左右。 关键词：介孔材料；不饱和聚酯；热性能；电性能 中图分类号：TM215.1；TQ323.4+2 文献标志码：A 文章编号：1009-9239（2014 ）02-0041-04 Preparation and Properties Study of SBA-15/Unsaturated Polyester Resin Lu Fengying, Lv Jian, Hu Shulong, Zhang Zhen, Liu Huashan, Zeng Deming (College of Material Science and Engineering, Key Laboratory of New Processing Technology for Nonferrous Metals and Materials, Ministry of Education, Ministry-province Jointly-constructed Cultivation Base for State Key Laboratory of Processing for Non-ferrous Metal and Featured Materials, Guilin university of Technology, Guilin 541004, China) Abstract: A mesoporous material/unsaturated polyester(SBA-15/UP) composite resin was prepared through in-situ polymerization. The properties of SBA- 15 and SBA-15/UP were characterized by X-ray diffraction (XRD), nitrogen adsorption-desorption, thermogravimetric analysis(TGA), and the effects of SBA-15 con- tent on the thermal properties and electrical properties of SBA- 15/UP were studied. The results show that the ordering of SBA- 15 decreases during the process of in-situ polymerization, and the diameter of SBA-15 reduces from 6.64 nm to 0.926 nm, which indicate that the UP molecular chain is embedded in the