《分析化学》位居中国期刊方阵quot;双高quot;期刊第九名.pdf

第 期 汪 正等：端视等离子体原子发射光谱法中内标法校正钠基体干扰 10 1225 Internal Standard Compensation for Interference of Sodium Matrix in Inductively Coupled Plasma Atomic Emission Spectrometry ! ， ， ， Wang Zheng Chen Tianyu Zhang Beihong Wu Xianxin （ ， ， ） Shanghai Institute of Ceramics Chinese Acadamy of Sciences Shanghai 200050 （ ） Abstract The non-spectroscopic interference of easiiy ionized eiements EIEs in axiai inductiveiy coupied piasma-atomic emission spectroscopy often makes its resuit deviate from accuracy . The interference due to variabie concentration of sodium and its compensation by using internai standard eiement yttrium were investigated . It was ， ， ， found that the combination of robust conditions i . e . high power and iow carrier gas fiow rate and seiecting some ion iines with sum of the ionization and excitation energy more than 10 eV couid compensate for interference from sodium matrix using yttrium 437 .494 nm internai standard eiements .