Thermodynamics of electrolytes. IV. Activity and osmotic coefficients for mixed electrolytes外文翻译.pdfVIP

5701 Acknowledgments. We are indebted to the Uni- tion. We also gratefully acknowledge the support of versity of Minnesota Computing Center for a grant the donors of the Petroleum Research Fund, adminis- supporting the calculations reported in this communica- tered by the American Chemical Society. Thermodynamics of Electrolytes. IV. Activity and Osmotic Coefficients for Mixed Electrolytes Kenneth S. Pitzer* and Janice J. Kim Contributionfrom the Inorganic Materials Research Division of the Lawrence Berkeley Laboratory and the Department of Chemistry, University of Californiu, Berkeley, California 94720. Received April 16, 1974 Abstract: An equation has been developed with the guidance of recent statistical theories of electrolytes which is designed for convenient and accurate representation and prediction of the thermodynamic properties of aqueous electrolytes including mixtures with any number of components. The three previous papers have given the theo- retical background and the evaluation of parameters for pure electrolytes of various charge types. The equation is here applied to a wide variety of mixed aqueous electrolytes at room temperature and at ionic strengths up to 6 M in many cases and occasionally even higher. The first objective is the prediction of properties of mixe