Quadrupolar transients, cosine correlation functions, and two-dimensional exchange spectra of non-selectively excited spin-32 nuclei A 7Li NMR study of the superionic conductor lithium indium phosphate》.pdf

Journal of Magnetic Resonance 260 (2015) 116–126 Contents lists available at ScienceDirect Journal of Magnetic Resonance journal homepage: www.else /locate/jmr Quadrupolar transients, cosine correlation functions, and two- dimensional exchange spectra of non-selectively excited spin-3/2 nuclei: A 7Li NMR study of the superionic conductor lithium indium phosphate M. Storek ⇑, R. Böhmer Fakultät Physik, Technische Universität Dortmund, 44221 Dortmund, Germany a r t i c l e i n f o a b s t r a c t Article history: Cos–cos stimulated echoes of non-selectively excited spin-3/2 nuclei were not exploited in studies of Received 30 July 2015 slow motional processes in solids and solid-like samples, so far. Based on a theoretical analysis of the Revised 3 September 2015 quadrupolar transients which hitherto obviously precluded the application of such echoes, their utility Available online 26 September 2015 7 is demonstrated for the example of Li NMR on the polycrystalline fast ion conductor lithium indium phosphate. Quadrupolar transients can adversely affect the shape of two- and three-pulse echo spectra Keywords: and strategies are successfully tested that mitigate their impact. Furthermore, by means of suitably Stimulated spin echoes adapted cos–cos echo sequences an effective suppression o