卷烟烟气中重要有害成分的分析的研究.pdf

摘要 4、采用剑桥滤片和XAD．4吸附树脂分别捕集卷烟主流烟气粒相和气相中的主 要半挥发性有机化合物，建立了GC—MS测定卷烟主流烟气中20种半挥发性 有机化合物(吡啶，苯乙烯等)的分析方法。与以往的冷溶液捕集方法相比， 本法操作简便、准确度高、重复性好，适用于大批量样品的分析。应用该方 法分析了2种参考卷烟和11种商品卷烟，研究结果表明：烷基取代吡啶类化 合物在主流烟气气相中的分布比例随着沸点升高呈指数关系降低，烟气粒相 中半挥发性有机化合物的输送量与焦油量相关性较为明显。 关键词：卷烟烟气 有害成分 酚类化合物 烟草特有亚硝胺 羰基化合物 半挥发性成分 11 Abstract ABSTRACT The ofthis wasto new objectivethesis develop and collection，separationanalysis methodforthe toxic chemicalsin smoke．The in major cigarette constituents major cigarette toxicalchemicalslistandtheadverseeffects smoke，major ofthesechemicalswerereviewed． The currentcollectionmethodsand chromatography weresummarized． analysistechnologies The methodsof4 oftoxicchemicals analysis groups including phenolic and in specific semi—volatile nitrosamines(TSNAs)，carbonylcompounds compounds smokewere cigarette developed． main Four wereincludedinthethesis aspects 1．A was that high-performanceliquid chromatographic(HPLC)methoddeveloped 7 in smoke．TobaccosmokeWas simultaneouslyquantifiesphenoliccompoundscigarette on collected extractis derivatization